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I^(-)(aq.)+MnO(4)^(-)(aq.)overset(H^(+))...

`I^(-)(aq.)+MnO_(4)^(-)(aq.)overset(H^(+))toX+Mn^(2+)(aq.)`
`I^(-)(aq.)+MnO_(4)^(-)(aq.) underset("weakly "OH^(-))overset("Neutral or")to Y+MnO_(2)`
`MnO_(4)^(-)(aq.)+Mn^(2+)(aq.) overset(ZnSO_(4)) to Z+4H^(+)`
Product X, Y and Z are respectively.

A

`I_(2),IO_(3)^(-),MnO_(2)`

B

`IO_(3)^(-),I_(2),MnO_(2)`

C

`I_(2),IO_(3)^(-),MnO_(4)^(2-)`

D

`IO_(3)^(-),I_(2),MnO_(4)^(2-)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reactions step by step, we will analyze each reaction separately to determine the products X, Y, and Z. ### Step 1: Analyze the first reaction **Reaction:** \[ I^{-} (aq) + MnO_{4}^{-} (aq) \overset{H^{+}}{\rightarrow} X + Mn^{2+} (aq) \] - **Oxidation and Reduction:** - The iodide ion \( I^{-} \) is oxidized to iodine \( I_{2} \) (oxidation state changes from -1 to 0). - The permanganate ion \( MnO_{4}^{-} \) is reduced to \( Mn^{2+} \) (oxidation state changes from +7 to +2). - **Product X:** Therefore, the product X is \( I_{2} \). ### Step 2: Analyze the second reaction **Reaction:** \[ I^{-} (aq) + MnO_{4}^{-} (aq) \underset{\text{weakly } OH^{-}}{\rightarrow} Y + MnO_{2} \] - **Oxidation and Reduction:** - In a neutral or weakly basic medium, the iodide ion \( I^{-} \) is oxidized to iodate \( IO_{3}^{-} \) (oxidation state changes from -1 to +5). - The permanganate ion \( MnO_{4}^{-} \) is reduced to manganese dioxide \( MnO_{2} \) (oxidation state changes from +7 to +4). - **Product Y:** Therefore, the product Y is \( IO_{3}^{-} \). ### Step 3: Analyze the third reaction **Reaction:** \[ MnO_{4}^{-} (aq) + Mn^{2+} (aq) \overset{ZnSO_{4}}{\rightarrow} Z + 4H^{+} \] - **Comproportionation Reaction:** - In this reaction, \( MnO_{4}^{-} \) (oxidation state +7) and \( Mn^{2+} \) (oxidation state +2) undergo a comproportionation reaction to form \( MnO_{2} \) (oxidation state +4). - The by-product of this reaction is \( 4H^{+} \). - **Product Z:** Therefore, the product Z is \( MnO_{2} \). ### Final Products - **Product X:** \( I_{2} \) - **Product Y:** \( IO_{3}^{-} \) - **Product Z:** \( MnO_{2} \) ### Summary of Products - X = \( I_{2} \) - Y = \( IO_{3}^{-} \) - Z = \( MnO_{2} \) ---

To solve the given reactions step by step, we will analyze each reaction separately to determine the products X, Y, and Z. ### Step 1: Analyze the first reaction **Reaction:** \[ I^{-} (aq) + MnO_{4}^{-} (aq) \overset{H^{+}}{\rightarrow} X + Mn^{2+} (aq) \] - **Oxidation and Reduction:** - The iodide ion \( I^{-} \) is oxidized to iodine \( I_{2} \) (oxidation state changes from -1 to 0). ...
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VK JAISWAL ENGLISH-TYPES OF REACTIONS-LEVEL 2
  1. In which of the following redox reaction precipitate is not formed?

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  2. Which metal sulphide is soluble in excess NH(3) solution?

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  3. I^(-)(aq.)+MnO(4)^(-)(aq.)overset(H^(+))toX+Mn^(2+)(aq.) I^(-)(aq.)+...

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  4. Br(2)+NaOH overset(R.T.) to Y+Z If Y gives precipitate with AgNO(3),...

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  5. (P)overset(Delta)to(Q)Metallic solid +(R)uarr+(S)uarr (X)overset(Del...

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  6. Iodine is not oxidized to iodic acid/iodicanhydride by:

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  7. Colourless gas that has oxidising as well as reducing properties:

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  8. Pb+Dil.HNO(3) overset(Warm)toP+Quarr+H(2)O Incorrect statement for Q...

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  9. Which reaction has positive value of DeltaG^(@)?

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  10. Which does not undergo comproportionation reaction?

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  11. Select the incorrect match:

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  12. Cu^(2+)(aq.)+X^(-)(aq.)overset(R.T.)toCuX darr+X(2) 'X' cannot be:

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  13. In which of the following reaction SO(2) gas is not produced?

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  14. Which metal gives NH(4)NO(3), when react with dilute HNO(3) acid?

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  15. Select the salt whose aqueous solution is not green:

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  16. Select the ion exchange reaction, which proceeds to forward direction ...

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  17. Which of the following metal hydroxide is not soluble in exces of NH(3...

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  18. Which of the following combination of reagents does not undergo redox ...

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  19. K(4)[Fe(CN)(6)]+M^(x+)(aq.)to underset("Coloured precipitate")(M(4)[Fe...

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  20. Sodium salt solution +AgNO(3)"soln."toColoured precipitate. If colou...

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