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Pb+Dil.HNO(3) overset(Warm)toP+Quarr+H(2...

`Pb+Dil.HNO_(3) overset(Warm)toP+Quarr+H_(2)O`
Incorrect statement for Q is:

A

Paramagnetic colourless gas

B

It is oxidized to paramagnetic coloured gas by air

C

It combines with `Fe_(2)(SO_(4))_(3)`

D

It is also obtained by disproportionation of `HNO_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of lead (Pb) with dilute nitric acid (HNO₃), we need to analyze the given statements about the products formed during the reaction. The reaction can be summarized as follows: 1. **Identify the Reaction**: The reaction between lead (Pb) and dilute nitric acid (HNO₃) when warmed produces lead(II) nitrate (Pb(NO₃)₂), nitrogen monoxide (NO), and water (H₂O). The balanced equation for this reaction is: \[ \text{Pb} + 4 \text{HNO}_3 \rightarrow \text{Pb(NO}_3\text{)}_2 + 2 \text{NO} + 2 \text{H}_2\text{O} \] 2. **Identify the Products**: In this reaction, the products are: - Pb(NO₃)₂ (lead(II) nitrate) - NO (nitrogen monoxide, which is gas Q) - H₂O (water) 3. **Analyze the Statements**: We need to evaluate the statements given in the question to find the incorrect one. - **Statement A**: "NO is paramagnetic in nature and colorless gas." - This statement is **true** because nitrogen monoxide (NO) has an unpaired electron, making it paramagnetic, and it is indeed colorless. - **Statement B**: "NO is oxidized to paramagnetic colored gas by air." - This statement is also **true**. When NO is oxidized, it forms nitrogen dioxide (NO₂), which is a reddish-brown gas, and NO₂ is paramagnetic as well. - **Statement C**: "NO combines with Fe₂(SO₄)₃." - This statement is **incorrect**. NO does not react with iron(III) sulfate (Fe₂(SO₄)₃) to form any significant products. Instead, NO can react with FeSO₄ (iron(II) sulfate) to form iron(III) oxide and other products, but not with Fe₂(SO₄)₃ directly. - **Statement D**: "NO is obtained by the depropagation of HNO₂." - This statement is **true**. Nitrous acid (HNO₂) can decompose to produce NO and HNO₃. 4. **Conclusion**: The incorrect statement among the options is **C**, as NO does not combine with Fe₂(SO₄)₃. ### Final Answer: The incorrect statement for Q is: **C. NO combines with Fe₂(SO₄)₃.**

To solve the question regarding the reaction of lead (Pb) with dilute nitric acid (HNO₃), we need to analyze the given statements about the products formed during the reaction. The reaction can be summarized as follows: 1. **Identify the Reaction**: The reaction between lead (Pb) and dilute nitric acid (HNO₃) when warmed produces lead(II) nitrate (Pb(NO₃)₂), nitrogen monoxide (NO), and water (H₂O). The balanced equation for this reaction is: \[ \text{Pb} + 4 \text{HNO}_3 \rightarrow \text{Pb(NO}_3\text{)}_2 + 2 \text{NO} + 2 \text{H}_2\text{O} \] ...
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PbO_(2)+HCl(dil.) overset(warm) to PbCl_(2)darr+Cl_(2)uarr+H_(2)O

PbO_(2)+HCl(dil.) overset(warm) to PbCl_(2)darr+Cl_(2)uarr+H_(2)O

Mg(s)+H_(2)O(l) overset("warm")toMg(OH)_(2)+H_(2)uarr

Mg(s)+H_(2)O(l) overset("warm")toMg(OH)_(2)+H_(2)uarr

Consider following reaction: Cl_(2)(g)+H_(2)O overset(R.T.)to P+Q If molecular weight of P is less than Q then incorrect statement is:

Pb_(3)O_(4)+HCl (dil.)overset(warm) to PbCl_(2)darr+Cl_(2)+H_(2)O

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VK JAISWAL ENGLISH-TYPES OF REACTIONS-LEVEL 2
  1. Iodine is not oxidized to iodic acid/iodicanhydride by:

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  2. Colourless gas that has oxidising as well as reducing properties:

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  3. Pb+Dil.HNO(3) overset(Warm)toP+Quarr+H(2)O Incorrect statement for Q...

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  4. Which reaction has positive value of DeltaG^(@)?

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  5. Which does not undergo comproportionation reaction?

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  6. Select the incorrect match:

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  7. Cu^(2+)(aq.)+X^(-)(aq.)overset(R.T.)toCuX darr+X(2) 'X' cannot be:

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  8. In which of the following reaction SO(2) gas is not produced?

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  9. Which metal gives NH(4)NO(3), when react with dilute HNO(3) acid?

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  10. Select the salt whose aqueous solution is not green:

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  11. Select the ion exchange reaction, which proceeds to forward direction ...

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  12. Which of the following metal hydroxide is not soluble in exces of NH(3...

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  13. Which of the following combination of reagents does not undergo redox ...

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  14. K(4)[Fe(CN)(6)]+M^(x+)(aq.)to underset("Coloured precipitate")(M(4)[Fe...

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  15. Sodium salt solution +AgNO(3)"soln."toColoured precipitate. If colou...

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  16. Chlorine gas is not produced by heating:

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  17. Which of the following anion does not prodcue prepitate with BaCl(2) s...

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  18. Which of the following compound is completely water soluble?

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  19. Which chemical reaction contains incorrect products?

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  20. Which of the following compound undergoes disproportionation in presen...

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