Home
Class 12
CHEMISTRY
P(4)+SOCl(2) overset(Delta)toProducts ...

`P_(4)+SOCl_(2) overset(Delta)to`Products
Find out total number of non-planar and polar molecules of products in balanced equation for one mole of `P_(4)`.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will follow these steps: ### Step 1: Write the Reaction We start with the reaction of phosphorus (P₄) with thionyl chloride (SOCl₂). The balanced chemical equation for the reaction is: \[ P_4 + 8 SOCl_2 \rightarrow 4 PCl_3 + 4 SO_2 + 2 S_2Cl_2 \] ### Step 2: Identify the Products From the balanced equation, we have three products: 1. Phosphorus trichloride (PCl₃) 2. Sulfur dioxide (SO₂) 3. Disulfur dichloride (S₂Cl₂) ### Step 3: Determine the Geometry of Each Product Next, we need to analyze the geometry of each product to determine if they are planar or non-planar. 1. **PCl₃**: - Phosphorus has five valence electrons and forms three bonds with chlorine atoms, leaving one lone pair. - The molecular geometry is trigonal pyramidal, which is **non-planar**. 2. **SO₂**: - Sulfur has six valence electrons and forms two bonds with oxygen atoms, with one lone pair remaining. - The molecular geometry is bent (or V-shaped), which is **planar**. 3. **S₂Cl₂**: - Each sulfur atom forms a bond with another sulfur atom and two chlorine atoms. - The structure is non-linear, and the geometry is also **non-planar**. ### Step 4: Determine Polarity Now we will check the polarity of each product: 1. **PCl₃**: - It is a polar molecule due to the presence of a lone pair on phosphorus and the electronegativity difference between phosphorus and chlorine. 2. **SO₂**: - It is also a polar molecule due to its bent shape and the difference in electronegativity between sulfur and oxygen. 3. **S₂Cl₂**: - It is a polar molecule as well, due to the difference in electronegativity between sulfur and chlorine and its non-planar structure. ### Step 5: Count Non-Planar and Polar Molecules Now we summarize the findings: - **Non-Planar and Polar Molecules**: - PCl₃ (1) - S₂Cl₂ (1) - **Planar and Polar Molecules**: - SO₂ (1) ### Conclusion The total number of non-planar and polar molecules from the products is: - PCl₃: 4 moles (from the balanced equation) - S₂Cl₂: 2 moles (from the balanced equation) Thus, the total number of non-planar and polar molecules is: \[ 4 \, (PCl_3) + 2 \, (S_2Cl_2) = 6 \] ### Final Answer The total number of non-planar and polar molecules of products in the balanced equation for one mole of P₄ is **6**. ---

To solve the problem, we will follow these steps: ### Step 1: Write the Reaction We start with the reaction of phosphorus (P₄) with thionyl chloride (SOCl₂). The balanced chemical equation for the reaction is: \[ P_4 + 8 SOCl_2 \rightarrow 4 PCl_3 + 4 SO_2 + 2 S_2Cl_2 \] ### Step 2: Identify the Products From the balanced equation, we have three products: ...
Promotional Banner

Topper's Solved these Questions

  • TYPES OF REACTIONS

    VK JAISWAL ENGLISH|Exercise MATCH THE COLUMN|14 Videos
  • s-BLOCK ELEMENTS

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|2 Videos

Similar Questions

Explore conceptually related problems

P_(4)+6Cl_(2) overset(Delta)toPCl_(3)

P_(4)+6Cl_(2) overset(Delta)toPCl_(3)

P_(4)+10Cl_(2)overset(Delta)toPCl_(5)

P_(4)+10Cl_(2)overset(Delta)toPCl_(5)

The total number of carboxylic acid groups in the product P is

P_(4)+NaOH underset("warm")to Products. Write the products

Copper sulphate reacts with NaCN to form a cyanide complex. Write the balanced equation and find the number of NaCN molecules involved in the equation for one mole of CuSO_(4) .

FeC_(2)O_(4)overset(Delta)to products Number of diamagnetic products=x Number of unpaired electrons in paramagnetic products=y report your answer as (x+y)

Total number of hydroxyl groups present in a molecule of the major product P is________.

VK JAISWAL ENGLISH-TYPES OF REACTIONS-SUBJECTIVE PROBLEMS
  1. Find total number of metal cations which are ppted as metal sulphide o...

    Text Solution

    |

  2. Consider the following reaction P(4)+KOH to PH(3)+X How many P-H bon...

    Text Solution

    |

  3. Which of the following species/reagent can reduce Fe^(3+)(aq.) into Fe...

    Text Solution

    |

  4. Find out number ionic compound(s0 which is/are water insoluble at room...

    Text Solution

    |

  5. Find the value of expression |x-y| for following compounds. where, ...

    Text Solution

    |

  6. Find out total number of coloured compound(s) from following: BaCO(3...

    Text Solution

    |

  7. Find out total number of cation(s) that produce precipitate with aqueo...

    Text Solution

    |

  8. P(4)+SOCl(2) overset(Delta)toProducts Find out total number of non-p...

    Text Solution

    |

  9. What is average oxidation state state of sulphur in product formed in ...

    Text Solution

    |

  10. find out total number of coloured/black water insoluble compound(s) fr...

    Text Solution

    |

  11. Find out total number of compounds which on heating undergo redox reac...

    Text Solution

    |

  12. How many following ammonium salts will evolve NH(3) gas on heating? ...

    Text Solution

    |

  13. How many following metals evolve NO (Nitric oxide) gas with dil. HNO(3...

    Text Solution

    |

  14. Find number of basic radicals among the following cations, which can f...

    Text Solution

    |

  15. Calculate difference between oxidation state of chromium (Cr) in blue ...

    Text Solution

    |

  16. If hydrolysis of interhalogen compound can be represented by following...

    Text Solution

    |

  17. Total number of species that can be oxidzed by acidic permanganate ion...

    Text Solution

    |

  18. How many following metals evolve N(2)O gas with dil. HNO(3) (20%) Cr...

    Text Solution

    |

  19. How many following ammonium salts will evolve NH(3) gas on heating? ...

    Text Solution

    |

  20. Find out the number of cation (s) which form(s) black ppt. (soluble in...

    Text Solution

    |