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The van der Waal's equation of state for...

The van der Waal's equation of state for some gases can be expressed as :
`(P + (a)/( V^(2))) ( V - b) = RT`
Where `P` is the pressure , `V` is the molar volume , and `T` is the absolute temperature of the given sample of gas and `a, b , and R` are constants.
In the above problem , the dimensional formula for `RT` is same as that of

A

Energy

B

Force

C

Specific heat

D

Latent heat

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The correct Answer is:
To find the dimensional formula for \( RT \) in the van der Waals equation, we can start by recalling the ideal gas equation, which is given by: \[ PV = RT \] ### Step 1: Understand the variables - \( P \) is the pressure. - \( V \) is the volume (specifically, molar volume). - \( T \) is the absolute temperature. - \( R \) is the universal gas constant. ### Step 2: Find the dimensional formula for pressure \( P \) Pressure \( P \) is defined as force per unit area. The dimensional formula for force is given by: \[ \text{Force} = \text{mass} \times \text{acceleration} = M \cdot L \cdot T^{-2} \] where: - \( M \) is the dimension of mass, - \( L \) is the dimension of length, - \( T \) is the dimension of time. The area has the dimension: \[ \text{Area} = L^2 \] Thus, the dimensional formula for pressure \( P \) is: \[ P = \frac{\text{Force}}{\text{Area}} = \frac{M \cdot L \cdot T^{-2}}{L^2} = M \cdot L^{-1} \cdot T^{-2} \] ### Step 3: Find the dimensional formula for volume \( V \) Volume \( V \) has the dimensional formula: \[ V = L^3 \] ### Step 4: Substitute into the ideal gas equation From the ideal gas equation \( PV = RT \), we can express \( R \) in terms of \( P \), \( V \), and \( T \): \[ R = \frac{PV}{T} \] ### Step 5: Find the dimensional formula for \( RT \) Now, substituting the dimensional formulas we found: 1. The dimensional formula for \( P \) is \( M \cdot L^{-1} \cdot T^{-2} \). 2. The dimensional formula for \( V \) is \( L^3 \). 3. The dimensional formula for \( T \) is \( \Theta \) (temperature). Substituting these into the formula for \( R \): \[ R = \frac{M \cdot L^{-1} \cdot T^{-2} \cdot L^3}{\Theta} = \frac{M \cdot L^{2} \cdot T^{-2}}{\Theta} \] Now, we can find the dimensional formula for \( RT \): \[ RT = R \cdot T = \left(\frac{M \cdot L^{2} \cdot T^{-2}}{\Theta}\right) \cdot \Theta = M \cdot L^{2} \cdot T^{-2} \] ### Conclusion Thus, the dimensional formula for \( RT \) is: \[ M \cdot L^{2} \cdot T^{-2} \]

To find the dimensional formula for \( RT \) in the van der Waals equation, we can start by recalling the ideal gas equation, which is given by: \[ PV = RT \] ### Step 1: Understand the variables - \( P \) is the pressure. ...
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