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From the following statements concerning...

From the following statements concerning ideal gas at any given temperature T, select the correct one (s)

A

The coefficient of volume expansion at constant pressure is the same for all ideal gases.

B

The average translational kinetic energy per molecule of oxygen gas is `3kT`, k being the Boltzmann constant.

C

The mean free path of molecules increases with decrease in pressure.

D

In a gaseous mixture, the average translational kinetic energy of the molecules of each component is different.

Text Solution

Verified by Experts

The correct Answer is:
A, C

For `1` mole of an ideal gas
`pV=RT` (i)
at constant pressure:
`PdV=RdT`
From Eqs. (i) and (ii), we get (ii)
`(dV)/(V)=(dT)/(T)`
The coefficient of volume expansion at constant pressure is given by
`(dV)/(VdT)=(1)/(T)`
same for all gases at same temperature.
The average translational kinetic energy per molecule is `(3//2)kT` and not `3kT` . With decrease in pressure, volume of the gas increases so its mean free path increases. [Option `(c)`]
The average translational kinetic energy of the molecules is independent of their nature, so each component of the gasesous mixture will have the some value of average translational kinetic energy.
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