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Which one of the following gases possess...

Which one of the following gases possesses the largest internal energy

A

2 moles of helium occupying 1 `m^(3)` at 300 K

B

56 kg of nitrogen at `10^(7) Nm^(-2)` and 300 K

C

8 grams of oxygen at 8 atm and 300 K

D

`6 xx 10^(26)` molecules of argon occupying `40 m^(3)` at 900 K

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The correct Answer is:
To determine which gas possesses the largest internal energy, we can use the formula for internal energy (U) of an ideal gas, which is given by: \[ U = N C_V T \] where: - \( N \) = number of moles of the gas - \( C_V \) = molar heat capacity at constant volume - \( T \) = absolute temperature in Kelvin ### Step-by-Step Solution: 1. **Identify the Gases and Their Properties:** - Helium: 1 mole, \( V = 1 \, \text{m}^3 \), \( T = 300 \, \text{K} \) - Nitrogen: 56 kg, \( P = 10^6 \, \text{N/m}^2 \), \( T = 300 \, \text{K} \) - Oxygen: 8 g, \( P = 8 \, \text{atm} \), \( T = 300 \, \text{K} \) - Argon: \( 6 \times 10^{26} \) molecules, \( V = 40 \, \text{m}^3 \), \( T = 900 \, \text{K} \) 2. **Calculate the Number of Moles (N) for Each Gas:** - For Helium: \[ N = 1 \, \text{mole} \] - For Nitrogen: \[ \text{Molar mass of } N_2 = 28 \, \text{g/mol} \] \[ N = \frac{56000 \, \text{g}}{28 \, \text{g/mol}} = 2000 \, \text{moles} \] - For Oxygen: \[ \text{Molar mass of } O_2 = 32 \, \text{g/mol} \] \[ N = \frac{8 \, \text{g}}{32 \, \text{g/mol}} = 0.25 \, \text{moles} \] - For Argon: \[ \text{Number of moles} = \frac{6 \times 10^{26}}{6.022 \times 10^{23}} \approx 1000 \, \text{moles} \] 3. **Determine the Molar Heat Capacity (C_V) for Each Gas:** - For Helium (monatomic): \[ C_V = \frac{3}{2} R \] - For Nitrogen (diatomic): \[ C_V = \frac{5}{2} R \] - For Oxygen (diatomic): \[ C_V = \frac{5}{2} R \] - For Argon (monatomic): \[ C_V = \frac{3}{2} R \] 4. **Calculate Internal Energy (U) for Each Gas:** - For Helium: \[ U_{He} = 1 \cdot \frac{3}{2} R \cdot 300 = 450 R \] - For Nitrogen: \[ U_{N_2} = 2000 \cdot \frac{5}{2} R \cdot 300 = 1500000 R \] - For Oxygen: \[ U_{O_2} = 0.25 \cdot \frac{5}{2} R \cdot 300 = 187.5 R \] - For Argon: \[ U_{Ar} = 1000 \cdot \frac{3}{2} R \cdot 900 = 1350000 R \] 5. **Compare the Internal Energies:** - \( U_{He} = 450 R \) - \( U_{N_2} = 1500000 R \) - \( U_{O_2} = 187.5 R \) - \( U_{Ar} = 1350000 R \) From the calculations, we can see that the internal energy of Nitrogen is the largest. ### Conclusion: The gas that possesses the largest internal energy is **Nitrogen** (56 kg at \( 10^6 \, \text{N/m}^2 \) and 300 K). ---
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