Home
Class 11
CHEMISTRY
A compound on analysis gave the followin...

A compound on analysis gave the following percentage composition by weight: hydrogen = 9.09, oxygen = 36.36 carbon = 54.55
Its `VD` is 44. Find the molecular formula of the compound.

Text Solution

AI Generated Solution

The correct Answer is:
To find the molecular formula of the compound based on the given percentage composition and vapor density, follow these steps: ### Step 1: Calculate the number of moles of each element We start by converting the percentage composition of each element into moles. - **Carbon (C)**: \[ \text{Moles of C} = \frac{\text{mass of C}}{\text{molar mass of C}} = \frac{54.55 \, \text{g}}{12 \, \text{g/mol}} = 4.54 \, \text{moles} \] - **Hydrogen (H)**: \[ \text{Moles of H} = \frac{\text{mass of H}}{\text{molar mass of H}} = \frac{9.09 \, \text{g}}{1 \, \text{g/mol}} = 9.09 \, \text{moles} \] - **Oxygen (O)**: \[ \text{Moles of O} = \frac{\text{mass of O}}{\text{molar mass of O}} = \frac{36.36 \, \text{g}}{16 \, \text{g/mol}} = 2.27 \, \text{moles} \] ### Step 2: Determine the simplest mole ratio Next, we need to find the simplest ratio of moles for each element by dividing each by the smallest number of moles calculated. - **Carbon**: \[ \frac{4.54}{2.27} = 2 \] - **Hydrogen**: \[ \frac{9.09}{2.27} = 4 \] - **Oxygen**: \[ \frac{2.27}{2.27} = 1 \] ### Step 3: Write the empirical formula From the simplest mole ratios, we can write the empirical formula: \[ \text{Empirical formula} = C_2H_4O \] ### Step 4: Calculate the empirical formula weight Now, we calculate the empirical formula weight: \[ \text{Empirical formula weight} = (2 \times 12) + (4 \times 1) + (1 \times 16) = 24 + 4 + 16 = 44 \, \text{g/mol} \] ### Step 5: Use vapor density to find molecular weight Given that the vapor density (VD) is 44, we can find the molecular weight: \[ \text{Molecular weight} = 2 \times \text{Vapor Density} = 2 \times 44 = 88 \, \text{g/mol} \] ### Step 6: Calculate the n factor Now, we calculate the n factor: \[ n = \frac{\text{Molecular weight}}{\text{Empirical formula weight}} = \frac{88}{44} = 2 \] ### Step 7: Determine the molecular formula Finally, we can find the molecular formula: \[ \text{Molecular formula} = n \times \text{Empirical formula} = 2 \times C_2H_4O = C_4H_8O_2 \] ### Conclusion The molecular formula of the compound is: \[ \text{Molecular formula} = C_4H_8O_2 \] ---

To find the molecular formula of the compound based on the given percentage composition and vapor density, follow these steps: ### Step 1: Calculate the number of moles of each element We start by converting the percentage composition of each element into moles. - **Carbon (C)**: \[ \text{Moles of C} = \frac{\text{mass of C}}{\text{molar mass of C}} = \frac{54.55 \, \text{g}}{12 \, \text{g/mol}} = 4.54 \, \text{moles} ...
Promotional Banner

Topper's Solved these Questions

  • SOME BASIC CONCEPTS AND MOLE CONCEPT

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Subjective (Limiting Reagent)|2 Videos
  • SOME BASIC CONCEPTS AND MOLE CONCEPT

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Subjective (Empirical And Molecular Formulae)|4 Videos
  • SOME BASIC CONCEPTS AND MOLE CONCEPT

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 1.2 Fill In The Blanks|1 Videos
  • S-BLOCK GROUP 2 - ALKALINE EARTH METALS

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 5.1 Objective|2 Videos
  • STATES OF MATTER

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Ture False)|25 Videos

Similar Questions

Explore conceptually related problems

A compound on analysis gave the following percentage composition : Na= 14.31%, S = 9.97%, H = 6.22%, O = 69.50%. Calculate the molecular formula of the compound on the assumption that all the hydrogen in the compound is present in combination with oxygen as water of crystallisation. Molecular mass of the compound is 322. (At. wt. of Na = 23, S = 32, H = 1, O = 16)

A compound has the following percentage composition by mass : Carbon = 54.55%, Hydrogen = 9.09% and Oxygen = 36.26%. Its vapour density is 44. Find the Empirical and molecular formula of the compound. (H = 1, C = 12,0 = 16)

A crystalline compound when heated became anhydrous by losing 51.2 % of the mass. On analysis, the anhydrous compound gave the following percentage composition: Mg = 20.0 %, S = 26.66 % and O = 53.33 %, Calculate the molecular formula of the anhydrous compound and crystalline compound. The molecular mass of anhydrous compound is 120 u.

A compound has the following percentage composition by mass: carbon 14.4%, hydrogen 1.2% and chlorine 84.5%. Determine the empirical formula of this compound. Work correct to 1 decimal place. (H = 1, C = 12, CI = 35.5)

A compound has the following percentage composition by mass: Carbon - 54.55%, Hydrogen - 9.09% Its vapour density is 50. Find the Empirical formula. (H = 1; C = 12; O = 16).

A compound on analysis was found to contain the following composition : Na=14.31%,S=9.97%,O=69.50 %and H=6.22 % Calculate the molecular formula of the compound assuming that the whole of hydrogen in the compound is present as water of crystallisation. Molecular mass of the compound is 322.

A substance on analysis, gave the following percentage composition : Na = 43.4 %, C = 11.3%, O = 45.3 %. Calculate the empirical formula. (Na = 23, C = 12, O = 16).

A substance on analysis, gave the following percentage composition : Na = 43.4 %, C = 11.3%, O = 45.3 %. Calculate the empirical formula. (Na = 23, C = 12, O = 16).

The compound A has the following percentage composition by mass : carbon 26. 7%, oxygen 71.1 %, hydrogen 2.2%. Determine the empirical formula of A. (Work to one decimal place) (H = 1, C = 12, O = 16). If the relative molecular mass of A is 90, what is the molecular formula of A ?

In a compound Carbond =52.2% , Hydrogen =13% , Oxygen =34.8% are present vapour density of the compound is 46. Calculate molecular formula of the compound ?