Home
Class 11
CHEMISTRY
P4 undergoes disproportionation in basic...

`P_4` undergoes disproportionation in basic medium to give `PH_3` (phosphine) and `H_2PO^(ɵ)` (dihydrogen hypophoshite ion). Atomic weight of P is 31.

Text Solution

AI Generated Solution

To solve the problem of phosphorus undergoing disproportionation in a basic medium to form phosphine (PH₃) and dihydrogen hypophosphite ion (H₂PO₂⁻), we will follow these steps: ### Step 1: Identify the Disproportionation Reaction Phosphorus (P₄) is undergoing disproportionation, which means it is both oxidized and reduced. The products are phosphine (PH₃) and dihydrogen hypophosphite ion (H₂PO₂⁻). ### Step 2: Write the Half-Reactions 1. **Reduction Half-Reaction**: \[ ...
Promotional Banner

Topper's Solved these Questions

  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 3.1|3 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 3.2|3 Videos
  • STATES OF MATTER

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Ture False)|25 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives (Subjective)|23 Videos

Similar Questions

Explore conceptually related problems

Br_2 undergoes disproportionation reaction in basic medium to give Br^(ɵ) ion and BrO_3^(ɵ) (bromate) ion in reduction and oxidation reaction.

18 " mL of " 1.0 M Br_(2) solution undergoes complete disproportionation in basic medium to Br^(The hardness of water in terms of ) and BrO_(3)^(ɵ) . Then the resulting solution required 45 " mL of " As^(3+) solution to reduce BrO_(3)^(ɵ) to Br^(ɵ) . As^(3+) is oxidised to As^(5+) which statements are correct?

The Mn^(3+) ion is unstable in solution and undergoes disproportionation reaction to give Mn^(+2), MnO_(2) , and H^(o+) ion. Write a balanced ionic equation for the reaction.

In PO_(4)^(3-) ion the formal charge on the oxygen atom of P-O bond is

In PO_(4)^(3-) ion the formal charge on the oxygen atom of P-O bond is

Equivalent weight of H_(3)PO_(2) when it disproportionates into PH_(3) and H_(3)PO_(3) is (mol.wt. of H_(3)PO_(2)=M )

The xenate ion (HXeO_(4)^(-)) undergoes disproportionation reaction to produce perxenate ion XeO_(5)^(4-) 2HXeO_(4)^(-)+2OH^(-)toXeO_(6)^(4-)+Xe+O_(2)+2H_(2)O The shape of xenate ion and perxenate ions is respectively:

The oxidation number of phosphorus in PO_(4)^(3-), P_(4)O_(10) , and P_(2)O_(7)^(4-) is

How many moles of O are present in 4.9 g of H_(3) PO_(4) ? (Atomic weight of P, O and H = 31, 16, 1 )

Balance the following equations in basic medium by ion electron method and oxidation number method and identify the oxidising agent and the reducing agent. P_(4)(s)+OH^(-)(aq)toPH_(3)(g)+H_(2)PO_(2)^(-)(aq)

CENGAGE CHEMISTRY ENGLISH-STOICHIOMETRY-Archives Subjective
  1. P4 undergoes disproportionation in basic medium to give PH3 (phosphine...

    Text Solution

    |

  2. In the analysis of 0.1 of sample of feldspar, 0.118 g of mixture of Na...

    Text Solution

    |

  3. 5 " mL of " a gas A containing only C and H was mixed with an excess o...

    Text Solution

    |

  4. One litre of mixture of CO and CO(2) is passed through red hot charcoa...

    Text Solution

    |

  5. Find out the equivalent weight of H(3) PO(4)in the reaction: Ca(OH)(...

    Text Solution

    |

  6. Hydroxylamine reduces Fe^(3+) accoeding to the following reaction: 2...

    Text Solution

    |

  7. An organic compound C(x)H(2y)O(y) was burnt with twice the amount of o...

    Text Solution

    |

  8. 4.08 g of a mixture of BaO and an unknown carbonate MCO(3) was heated ...

    Text Solution

    |

  9. When 16.8 g of a white solid X was heated 4.4 g of an acid gas A which...

    Text Solution

    |

  10. 2.68xx10^(-3) moles of solution containing anion A^(n+) require 1.61xx...

    Text Solution

    |

  11. 5 mL of 8 N HNO(3), 4.8 mL of 5 N HCl, and a certain volume of 17 m H(...

    Text Solution

    |

  12. What is the weight of sodium bromate and molarity of solution to prepa...

    Text Solution

    |

  13. A sample of hydrazine sulphate (N2H6SO4) was dissolved in 100 " mL of ...

    Text Solution

    |

  14. An equal volume of reducing agent is titrated separately with 1 M KMnO...

    Text Solution

    |

  15. n-Butance (C(4)H(10)) is produced by monobromation of C(2)H(6) followe...

    Text Solution

    |

  16. A mixture of H(2)C(2)O(4) and NaHC(2)O(4) weighing 2.02 g was dissolve...

    Text Solution

    |

  17. A solid mixture(5.000 g) consisting of lead nitrate and sodium nitrate...

    Text Solution

    |

  18. A solution of 0.2 g of a compound containing Cu^(2+) and C(2)O(4)^(2-)...

    Text Solution

    |

  19. 1.0 g of Fe2O3 solid of 55.2% purity is dissolved in acid. The solutio...

    Text Solution

    |

  20. A 2.0 g sample of a mixture containing sodium carbonate, sodium bicarb...

    Text Solution

    |

  21. 1.0 g of AgNO3 is dissolved in 50 " mL of " water It is titrated with ...

    Text Solution

    |