Home
Class 11
CHEMISTRY
Hydroxylamine reduces Fe^(3+) accoeding ...

Hydroxylamine reduces `Fe^(3+)` accoeding to the following reaction:
`2NH_2OH+4Fe^(3+)toH_2O+4Fe^(2+)+4H^(o+)+N_2O`
`Fe^(2+)` produced is is estimated by titration with `KMnO_4` solution A 10 mL sample of `NH_2OH` is diluted to 1000 mL. 50 " mL of " this diluted sample is boiled with excess of Fe (III) solution. The resulting solution required 12 " mL of " 0.02 M `KMnO_4` for complete oxidation. Determine the strength of `NH_2OH`.

Text Solution

AI Generated Solution

To solve the problem, we will follow these steps: ### Step 1: Write the balanced equation for the reaction with KMnO4 The balanced equation for the titration of Fe²⁺ with KMnO₄ is: \[ \text{MnO}_4^- + 8 \text{H}^+ + 5 \text{Fe}^{2+} \rightarrow \text{Mn}^{2+} + 4 \text{H}_2\text{O} + 5 \text{Fe}^{3+} \] ### Step 2: Calculate the normality of KMnO4 solution Given that 12 mL of 0.02 M KMnO₄ solution is used: ...
Promotional Banner

Topper's Solved these Questions

  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 3.1|3 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 3.2|3 Videos
  • STATES OF MATTER

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Ture False)|25 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives (Subjective)|23 Videos

Similar Questions

Explore conceptually related problems

Hydroxylamine reduce iron (III) according to the equation : 2NH_(2)OH + 4 Fe^(3+) rarr N_(2)O(g)uarr + H_(2)O + 4Fe^(2+) + 4H^(+) Iron (II) thus produced is estimated by titration with a standard permanganate solution. The reaction is MnO_(4)^(-) + 5 Fe^(2+) + 8H^(+) rarr Mn^(2+) + 5Fe^(3+) + 4H_(2)O A 10 mL sample of hydroxylamine solution was diluted to 1 litre. 50 mL of this diluted solution was boiled with an excess of iron (III) solution. The resulting solution required 12 mL of 0.02 M KMnO_(4) solution for complete oxidation of iron (II). Calculate the weight of hydroxylamine in one litre of the original solution

A sample of 28 mL of H_(2) O_(2) (aq) solution required 10 mL of 0.1 M KMnO_(4) (aq) solution for complete reaction in acidic medium. What is the valume strength of H_(2)O_(2) ?

638.0 g of CuSO_(4) solution is titrated with excess of 0.2 M KI solution. The liberated I_(2) required 400 " mL of " 1.0 M Na_(2)S_(2)O_(3) for complete reaction. The percentage purity of CuSO_(4) in the sample is

A 0.46 g sample of As_(2)O_(3) required 25.0 " mL of " KMnO_(4) solution for its titration. The molarity of KMnO_(4) solution is

A sample of MnSO_4.4H_2O is reacted in air to give Mn_3O_4 . The residue Mn_3O_4 is dissolved in 100 " mL of " (N)/(12)FeSO_4 containing H_2SO_4 The solution reacts completely with 50 " mL of " KMnO_4 . 25 " mL of " this KMnO_4 requires 30 " mL of " (N)/(10)FeSO_4 for complete oxidation determine the amount of MnSO_4.4H_2O in the sample.

0.2 g if a sample of H_2 O_2 required 10 ml of 1 N KMnO_4 for titration in acidic medium. The percentage purity of H_2 O_2 sample is:

A 3.4g sample of H_2 O_2 solution containing x% h_2O_2 by mass requires x mL of a KMnO_4 solution for complete oxidation under acidic condition. The molarity of KMnO_4 solution is :

25 mL of 0.50M H_(2)O_(2) solution is added to 50 mL of 0.20 M KMnO_(4) is acid solution. Which of the following statements is true?

20mL of 0.2MNaOH(aq) solution is mixed with 35mL of 0.1MNaOH(aq) solution and the resultant solution is diluted to 100mL. 40mL of this diluted solution reacted with 10% impure sample of oxalic acid (H_2C_2O_4) . The mass impure sample is :

20mL of H_(2)O_(2) after acidification with dilute H_(2)SO_(4) required 30mL of N/2 KMnO_(4) for complete oxidation. Calculate the percentage of H_(2)O_(2) in the solution. Equivalent mass of H_(2)O_(2)=17 .

CENGAGE CHEMISTRY ENGLISH-STOICHIOMETRY-Archives Subjective
  1. Hydroxylamine reduces Fe^(3+) accoeding to the following reaction: 2...

    Text Solution

    |

  2. In the analysis of 0.1 of sample of feldspar, 0.118 g of mixture of Na...

    Text Solution

    |

  3. 5 " mL of " a gas A containing only C and H was mixed with an excess o...

    Text Solution

    |

  4. One litre of mixture of CO and CO(2) is passed through red hot charcoa...

    Text Solution

    |

  5. Find out the equivalent weight of H(3) PO(4)in the reaction: Ca(OH)(...

    Text Solution

    |

  6. Hydroxylamine reduces Fe^(3+) accoeding to the following reaction: 2...

    Text Solution

    |

  7. An organic compound C(x)H(2y)O(y) was burnt with twice the amount of o...

    Text Solution

    |

  8. 4.08 g of a mixture of BaO and an unknown carbonate MCO(3) was heated ...

    Text Solution

    |

  9. When 16.8 g of a white solid X was heated 4.4 g of an acid gas A which...

    Text Solution

    |

  10. 2.68xx10^(-3) moles of solution containing anion A^(n+) require 1.61xx...

    Text Solution

    |

  11. 5 mL of 8 N HNO(3), 4.8 mL of 5 N HCl, and a certain volume of 17 m H(...

    Text Solution

    |

  12. What is the weight of sodium bromate and molarity of solution to prepa...

    Text Solution

    |

  13. A sample of hydrazine sulphate (N2H6SO4) was dissolved in 100 " mL of ...

    Text Solution

    |

  14. An equal volume of reducing agent is titrated separately with 1 M KMnO...

    Text Solution

    |

  15. n-Butance (C(4)H(10)) is produced by monobromation of C(2)H(6) followe...

    Text Solution

    |

  16. A mixture of H(2)C(2)O(4) and NaHC(2)O(4) weighing 2.02 g was dissolve...

    Text Solution

    |

  17. A solid mixture(5.000 g) consisting of lead nitrate and sodium nitrate...

    Text Solution

    |

  18. A solution of 0.2 g of a compound containing Cu^(2+) and C(2)O(4)^(2-)...

    Text Solution

    |

  19. 1.0 g of Fe2O3 solid of 55.2% purity is dissolved in acid. The solutio...

    Text Solution

    |

  20. A 2.0 g sample of a mixture containing sodium carbonate, sodium bicarb...

    Text Solution

    |

  21. 1.0 g of AgNO3 is dissolved in 50 " mL of " water It is titrated with ...

    Text Solution

    |