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50 g caustic soda is completely converte...

50 g caustic soda is completely converted into sodium chlorate and sodium chloride by the action of chlorine What weight of manganese dioxide and what volume of HCl (containing `300gL^(-1)`) were used for the production of necessary chlorine?

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To solve the problem, we will follow these steps: ### Step 1: Write the relevant chemical reactions The two reactions involved in the process are: 1. The reaction of manganese dioxide (MnO₂) with hydrochloric acid (HCl) to produce chlorine gas (Cl₂): \[ \text{MnO}_2 + 4 \text{HCl} \rightarrow \text{MnCl}_2 + \text{Cl}_2 + 2 \text{H}_2\text{O} ...
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In iodometric titrations, an oxidizing agent such as KNnO_(4), K_(2)Cr_(2)O_(7),CuSO_(4),H_(2)O_(2) is allowed to react in neutral medium or in acidic medium with excess of potassium iodide to liberate free iodine Kl+ oxidizon agent to l_(2) Free iodine is titrated against stanard reducing agent usually with sodium thiosulphate i.e., K_(2)Cr_(2)O_(7)+6Kl+7H_(2)SO_(4)toCr_(2)(SO_(4))_(3)+4K_(2)SO_(4)+7H_(2)O+l_(2) 2CuSO_(4)+4Kl to Cu_(2)l_(2)+2K_(2)SO_(4)+l_(2) l_(2)+Na_(2)S_(2)O_(3)to 2Nal+Na_(2)S_(4)O_(6) In iodometric titrations, starch solution is used as an indicator. Starch solution gives blue or violet colour with free iodine. At the end point, blue or violet colour disappear when iodine is completely changed to iodide. What volume of 0.40M Na_(2)S_(2)O_(3) would be required to reach with l_(2) liberated by adding 0.04 mole of Kl to 50 mL to 0.20 M CuSO_(4) solution?

Free iodine is titrated against standard reducing agent usually with sodium thiosulphate , i.e. K_(2)Cr_(2)O_(7) + 6Kl + 7H_(2)SO_(4) to Cr_(2)(SO_(4))_(3) + 4K_(2) SO_(4) + 7H_(2)O+l_(2) 2CuSO_(4) + 4Kl to Cu_(2)l_(2) + 2K_(2)SO_(4) + l_(2) l_(2) + Na_(2)S_(2)O_(3) to 2Nal + Na_(2)S_(4)O_(6) In iodometric titration, starch solution is used as an indicator. Starch solution gives blue or violet colour with free iodine .At the end point , blue or violet colour disappears when iodine is completely changed to iodide. What volume of 0.40 M Na_(2)S_(2)O_(3) would be required to react with l_(2) liberated by adding 0.04 mole of Kl to 50 ml of 0.20 M CuSO_(4) solution ?

CENGAGE CHEMISTRY ENGLISH-STOICHIOMETRY-Exercises Subjective
  1. Chlloride samples are prepared for analysis by using NaCl, KCl, NH4Cl ...

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  2. 2.1 g of a mixture of NaHCO3 and KCIO3 required 100 " mL of " 0.1 HCl ...

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  3. 50 g caustic soda is completely converted into sodium chlorate and sod...

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  4. A 1.0 g sample of KCIO3 was heated under such conditions that a part o...

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  7. 2 g of brass containing Cu and Zn only reacts with 3M HNO(3) solution....

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  8. A mass of 2.72 g of an alloy containing Pb, required for dissolved in ...

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  9. On passing 10.0 L of a gaseous mixture of NO(2) and N(2) at STP, throu...

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  10. A sample of pure CuO was reduced with H2 gas and H(2)O formed was coll...

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  11. A mixture of iron (II) and lead (II) caerbonates was calcined. As a re...

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  12. Calculate the percentage of oxalate ion in a given sample of oxalate s...

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  13. 0.56 g of limestrone was treated with oxalic acid to give CaC(2)O(4). ...

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  14. Calculate the weight of MnO(2) and the volume of HCl of specific gravi...

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  15. In the following reaction overset(ɵ)(O)H+S(2)O(3)^(2-)+Br(2)toSO(4)^...

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  16. Chlorine dioxide (ClO(2)) is used now days for water treatment rather ...

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  17. In the reaction given Mg(s)+NO(3)^(ɵ)+H(2)OtoMg(OH)(2)(s)+overset(ɵ)...

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  18. Calculate the percentage of Cr in a sample of dichromate ore if 1.0 g ...

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  19. Chile salt peter a source of NaNO(3) also contains NaIO(3) the NaIO(3)...

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  20. 0.5 g mixture of K(2)Cr(2)O(7) and KMnO(4) was treated with excess of ...

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