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Choose the correct statement:...

Choose the correct statement:

A

1 " mol of "`MnO_(4)^(ɵ)` ion can oxidise 5 " mol of "`Fe^(2+)` ion in acidic medium.

B

1 " mol of "`Cr_(2)O_(7)^(2-)` ion can oxidise 6 " mol of "`Fe^(2+)` ion in acidic medium.

C

1 " mol of "`Cu_(2)S` can be oxidised by 1.6 mole of `MnO_(4)^(ɵ)` ion in acidic medium.

D

1 " mol of "CuS can be oxidised by 1 " mol of "`Cr_(2)O_(7)^(2-)` ion in acidic medium.

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The correct Answer is:
To solve the question, we need to analyze each statement regarding the behavior of permanganate ions (MnO4^-), dichromate ions (Cr2O7^2-), iron ions (Fe^2+), copper(I) sulfide (Cu2S), and copper(I) sulfide (CuS) in acidic medium. ### Step-by-step Solution: 1. **Analyze Statement A:** - In acidic medium, 1 mole of permanganate ion (MnO4^-) gains 5 moles of electrons. - 1 mole of Fe^2+ loses 1 mole of electron. - Therefore, 1 mole of MnO4^- can oxidize 5 moles of Fe^2+. - **Conclusion:** Statement A is true. 2. **Analyze Statement B:** - In acidic medium, 1 mole of dichromate ion (Cr2O7^2-) gains 6 moles of electrons. - 1 mole of Fe^2+ loses 1 mole of electron. - Therefore, 1 mole of Cr2O7^2- can oxidize 6 moles of Fe^2+. - **Conclusion:** Statement B is true. 3. **Analyze Statement C:** - In acidic medium, 1 mole of permanganate ion (MnO4^-) gains 5 moles of electrons. - 1 mole of Cu2S loses 2 moles of electrons. - Since 1 mole of MnO4^- can oxidize 5 moles of Fe^2+, but Cu2S does not fit this ratio correctly, the statement is incorrect. - **Conclusion:** Statement C is false. 4. **Analyze Statement D:** - 1 mole of CuS can be oxidized by 1 mole of Cr2O7^2-. - In acidic medium, 1 mole of Cr2O7^2- gains 6 moles of electrons. - 1 mole of CuS loses 2 moles of electrons. - The stoichiometry does not match, making this statement incorrect. - **Conclusion:** Statement D is false. 5. **Final Conclusion:** - The correct statements are A and B. Therefore, the answer to the question is that options A and B are correct.

To solve the question, we need to analyze each statement regarding the behavior of permanganate ions (MnO4^-), dichromate ions (Cr2O7^2-), iron ions (Fe^2+), copper(I) sulfide (Cu2S), and copper(I) sulfide (CuS) in acidic medium. ### Step-by-step Solution: 1. **Analyze Statement A:** - In acidic medium, 1 mole of permanganate ion (MnO4^-) gains 5 moles of electrons. - 1 mole of Fe^2+ loses 1 mole of electron. - Therefore, 1 mole of MnO4^- can oxidize 5 moles of Fe^2+. ...
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CENGAGE CHEMISTRY ENGLISH-STOICHIOMETRY-Exercises Multiple Correct
  1. H(2)C(2)O(4) and NaHC(2)O(4) behave as acids as well as reducing agent...

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  2. A compound contains atom A, B and C . The oxidation number of A is +2,...

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  3. Choose the correct statement:

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  4. For the following balanced redox reaction: 2MnO(4)^(ɵ)+8H^(o+)+Br(2)...

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  5. Which of the following statements is/are correct about the followig re...

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  6. Which of the following statements is//are correct about 6.8% stregnth ...

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  7. Which of the following reactions is/are not intermolecular redox react...

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  8. 1 L sample of impure water containing sulphide ion is made ammoniacal ...

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  9. Which of the following statements is/are correct about the reaction. ...

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  10. Which of the following statements is/are correct in following reaction...

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  11. In which of the reaction,oxygen is an oxidant.

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  12. 56.0 g KOH, 138.0 g K(2)CO(3) and 100.0 g KHCO(3) is dissolved in wate...

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  13. x g of H2O2 requires 100mL of M//5 KMnO4 in a titration in a solution ...

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  14. A mixture of n(1) moles of Na(2)C(2)O(4) and NaHC(2)O(4) is titrated s...

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  15. 100 " mL of " 0.2 M Kal(OH)(2)CO(3) solution is completely neutralised...

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  16. Which of the following is/are correct about the redox reaction? MnO(...

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  17. 20 " mL of " H(2)O(2) is reacted completely with acidified K(2)Cr(2)O(...

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  18. Three different solution of oxidising agents. K(2)Cr(2)O(7),I(2), and ...

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  19. Consider the following reaction: KClO(3)(s)overset(Delta)toKCl(s)+O(...

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  20. 2.0 g of an elements is reacted with aqueous solution containing KOH a...

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