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For the following balanced redox reactio...

For the following balanced redox reaction:
`2MnO_(4)^(ɵ)+8H^(o+)+Br_(2)to2Mn^(2+)+2BrO_(3)^(ɵ)+2H_(2)O`
if the molecular weight of `MnO_(4)^(ɵ):Br_(2)` and `Br_(2)` be `M_(1)M_(2)` respectively, then

A

equivalent weight of `MnO_(4)^(ɵ)` is `(M_(1))/(5)`

B

Equivalents weight of `Br_(2)` is `(M_(2))/(10)`

C

The n-factor ratio of `MnO_(4)^(ɵ):Br_(2)is1:1`

D

none of these

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AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given balanced redox reaction and determine the equivalent weights and the ratio of the molecular weights of \( \text{MnO}_4^- \) and \( \text{Br}_2 \). ### Step-by-Step Solution: 1. **Identify the Oxidation States**: - In \( \text{MnO}_4^- \), manganese (Mn) has an oxidation state of +7. - In \( \text{Br}_2 \), bromine (Br) has an oxidation state of 0. 2. **Determine the Change in Oxidation States**: - For \( \text{MnO}_4^- \) going to \( \text{Mn}^{2+} \): - Change in oxidation state = +7 to +2 = 5 (reduction). - For \( \text{Br}_2 \) going to \( \text{BrO}_3^- \): - Change in oxidation state = 0 to +5 = 5 (oxidation for each Br). - Since there are 2 bromine atoms in \( \text{Br}_2 \), the total change is 10 (oxidation). 3. **Calculate the n-factor**: - The n-factor for \( \text{MnO}_4^- \) is 5 (since it gains 5 electrons). - The n-factor for \( \text{Br}_2 \) is 10 (since it loses 10 electrons). 4. **Determine Equivalent Weights**: - The equivalent weight of a substance is given by the formula: \[ \text{Equivalent Weight} = \frac{\text{Molecular Weight}}{\text{n-factor}} \] - For \( \text{MnO}_4^- \): \[ \text{Equivalent Weight} = \frac{M_1}{5} \] - For \( \text{Br}_2 \): \[ \text{Equivalent Weight} = \frac{M_2}{10} \] 5. **Establish the Ratio of Molecular Weights**: - From the equivalent weights, we have: \[ \frac{M_1}{5} \quad \text{and} \quad \frac{M_2}{10} \] - Setting the two equivalent weights equal gives: \[ \frac{M_1}{5} = \frac{M_2}{10} \] - Cross-multiplying leads to: \[ 10M_1 = 5M_2 \quad \Rightarrow \quad 2M_1 = M_2 \] - Thus, the ratio \( M_1 : M_2 = 1 : 2 \). ### Final Answer: The ratio of the molecular weights \( M_1 : M_2 \) is \( 1 : 2 \).

To solve the problem, we need to analyze the given balanced redox reaction and determine the equivalent weights and the ratio of the molecular weights of \( \text{MnO}_4^- \) and \( \text{Br}_2 \). ### Step-by-Step Solution: 1. **Identify the Oxidation States**: - In \( \text{MnO}_4^- \), manganese (Mn) has an oxidation state of +7. - In \( \text{Br}_2 \), bromine (Br) has an oxidation state of 0. ...
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