Home
Class 11
CHEMISTRY
F(2) can be prepared by reacting hexfluo...

`F_(2)` can be prepared by reacting hexfluoro magnante (IV) with antimony pentafluoride as:
`K_(2)KnF_(6)+SbF_(5)overset(150^(@)C)toKSbF_(6)+MnF_(3)+F_(2)` ltBrgt The number of equivalent of `K_(2)MnF_(6)` requried to react completely with one " mol of "`SbF_(5)` in the given reaction is

A

`1.52`

B

`5.0`

C

`0.5`

D

`4.0`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the number of equivalents of \( K_2MnF_6 \) required to react completely with one mole of \( SbF_5 \) in the given reaction. Let's break down the steps: ### Step 1: Write the balanced chemical equation The balanced reaction provided is: \[ K_2MnF_6 + 2SbF_5 \rightarrow 2KSbF_6 + MnF_3 + \frac{1}{2}F_2 \] ### Step 2: Identify the oxidation states In this reaction, we need to identify the changes in oxidation states to determine the n-factor for \( K_2MnF_6 \). - **For Manganese (Mn)**: - In \( K_2MnF_6 \), Mn is in the +4 oxidation state. - In \( MnF_3 \), Mn is in the +3 oxidation state. - Therefore, Mn goes from +4 to +3, which means it gains 1 electron. - **For Fluorine (F)**: - In \( SbF_5 \), F is in the -1 oxidation state. - In \( F_2 \), F is in the 0 oxidation state. - Thus, each F atom goes from -1 to 0, which means it loses 1 electron. Since there are 2 F atoms produced, a total of 2 electrons are lost. ### Step 3: Calculate the n-factor for \( K_2MnF_6 \) The n-factor is defined as the total number of moles of electrons gained or lost per mole of the substance. - For \( K_2MnF_6 \): - Mn contributes 1 electron (from +4 to +3). - For \( SbF_5 \): - 2 moles of \( SbF_5 \) contribute a total of 2 electrons (2 F atoms). Thus, the total change in electrons is: - \( K_2MnF_6 \) provides 1 electron. - \( SbF_5 \) consumes 2 electrons. ### Step 4: Determine the relationship between \( K_2MnF_6 \) and \( SbF_5 \) From the balanced equation, we see that: - 1 mole of \( K_2MnF_6 \) reacts with 2 moles of \( SbF_5 \). - Therefore, 1 mole of \( SbF_5 \) will react with \( \frac{1}{2} \) mole of \( K_2MnF_6 \). ### Step 5: Calculate the equivalents Since we have established that: - 1 mole of \( K_2MnF_6 \) is equivalent to 1 equivalent (because it provides 1 electron), - Thus, \( \frac{1}{2} \) mole of \( K_2MnF_6 \) will be equivalent to \( \frac{1}{2} \) equivalent. ### Final Answer The number of equivalents of \( K_2MnF_6 \) required to react completely with one mole of \( SbF_5 \) is: \[ \text{0.5 equivalents} \]

To solve the problem, we need to determine the number of equivalents of \( K_2MnF_6 \) required to react completely with one mole of \( SbF_5 \) in the given reaction. Let's break down the steps: ### Step 1: Write the balanced chemical equation The balanced reaction provided is: \[ K_2MnF_6 + 2SbF_5 \rightarrow 2KSbF_6 + MnF_3 + \frac{1}{2}F_2 \] ...
Promotional Banner

Topper's Solved these Questions

  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion Reasoning|15 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer|16 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct|30 Videos
  • STATES OF MATTER

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Ture False)|25 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives (Subjective)|23 Videos

Similar Questions

Explore conceptually related problems

F_(2) is formed by reacting K_(2) MnF_(6) with

How many moles of H_2O_2 will be requried to react completely with 1.5 " mol of " K[Cr(OH)_4] (potassium tetrahydroxochromate (I)) in basic medium?

Circle the rational number that is equivalent to (2)/(5) , (3)/(6)

6xx10^(-3) mole K_(2)Cr_(2) C_(7) reacts completely with 9xx10^(-3) mole X^(n+) to give XO_(3)^(-) and Cr^(3+) . The value of n is :

6 xx 10^(-3) mole K_2 Cr_2 O_7 reacts completely with 9 xx 10^(-3) mole X^(n+) to given XO_3^- and Cr_^(3+) . The value of n is :

For the reaction, 3Zn^(2+)+2K_(4)[Fe(CN)_(6)]rarr K_(2)Zn_(3)[Fe(CN)_(6)]_(2)+6K^(+) , what will be the equivalent weight of K_(4)[Fe(CN)_(6)] , if the molecular weight of K_(4)[Fe(CN)_(6)] is M ?

C_(6) H_(5) N_(2) Cl + "HBF"_(4) overset(Delta)(rarr) C_(6)H_(5)F + N_(2) + BF_(3) . The reaction is called

(A) Complete the following chemical reactions: (i) XeF_(4)+SbF_(5)to (ii) XeF_(6)+2H_(2)O to (iii) XeF_(6)+3H_(2)O to (B) Why could fluorine not be prepared for a long time from HF and metal fluorides either by electrolysis or by any chemical reaction ?

The rate of formation of C_(6)H_(6)+3H_(2) underset(k_(b))overset(k_(f))hArr C_(6)H_(12) for the forward reaction is first order with respect to C_(6)H_(6) and H_(12) each. Which one of the options is/are correct?

2C_(6)H_(5)CHO overset(NaOH) to C_(6)H_(5)CH_(2)OH + C_(6)H_(5)COONa The similar reaction can take place with which of the following aldehyde?

CENGAGE CHEMISTRY ENGLISH-STOICHIOMETRY-Exercises Single Correct
  1. RH(2) ( ion exchange resin) can replace Ca^(2+)d in hard water as. R...

    Text Solution

    |

  2. 100mL of H2O2 is oxidised by 100mL of 0.01M KMnO4 in acidic medium (Mn...

    Text Solution

    |

  3. F(2) can be prepared by reacting hexfluoro magnante (IV) with antimony...

    Text Solution

    |

  4. 3 " mol of "a mixture of FeSO(4) and Fe(2)(SO(4))(3) requried 100 " mL...

    Text Solution

    |

  5. 28 NO(3)^(-)+3As(2)S(3)+4H(2)O rarr 6AsO(4)^(3-)+28NO+9SO(4)^(2-)+H^(+...

    Text Solution

    |

  6. Which of the following reaction is oxidation- reduction?

    Text Solution

    |

  7. In the reaction A^(+x) + MnO(4)^() to AO(3)^() + Mn^(++) +(1)/(2)O, i...

    Text Solution

    |

  8. In the mixture of (NaHCO3 + Na2CO3), volume of HCI required is x mL wi...

    Text Solution

    |

  9. Which of the following does not represent redox reaction?

    Text Solution

    |

  10. 10 " mL of " NaHC(2)O(4) is oxidised by 10 " mL of " 0.02 M MnO(4)^(ɵ)...

    Text Solution

    |

  11. 1 mole of ferric oxalate is oxidised by x mole of MnO(4)^(-) in acidic...

    Text Solution

    |

  12. 2 "mole" N(2) and 3 "mole" H(2) gas are allowed to react in a 20 L fla...

    Text Solution

    |

  13. K(2)Cr(2)O(7) is obtained in the following steps: 2FeCrO(4)+2Na(2)CO...

    Text Solution

    |

  14. 40 mL 0.05 M solution of sodium sesquicarbonate dehydrate (Na(2)CO(3)....

    Text Solution

    |

  15. What volume of 0.05 M K(2)Cr(2)O(7) in acidic medium is needed for com...

    Text Solution

    |

  16. MnO(4)^(2-) (1 mole) in neutral aqueous medium is disproportionate to

    Text Solution

    |

  17. If equal volumes of 0.1 M KMnO(4) and 0.1 M K(2)Cr(2)O(7) solutions ar...

    Text Solution

    |

  18. 100 mL of 0.01 M KMnO(4) oxidised 100 mL H(2)O(2) in acidic medium. ...

    Text Solution

    |

  19. The volume strength of 1.5 N H(2)O(2) solution is

    Text Solution

    |

  20. The equivalent mass of MnSO4 is half of its molecular mass when it is ...

    Text Solution

    |