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In a mixture of He^(o+) gas H atom and H...

In a mixture of `He^(o+)` gas H atom and `He^(o+)` ions Are excited to three respective first excited subsepuenly , H atom transfers its total excitation energy to `He^(o+)`ions by collision .Assuming that Bohr model of an atom is applicable , answer the following question
The ratio of teh potential energy of the `n = 2` electron for H atom to the of `He^(o+)` ion is

A

`1//4`

B

`1//2`

C

4

D

3

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The correct Answer is:
To solve the problem, we need to find the ratio of the potential energy of the \( n = 2 \) electron for a hydrogen atom (\( H \)) to that of a helium ion (\( He^{+} \)). We will use the Bohr model of the atom to derive the necessary formulas. ### Step-by-Step Solution: 1. **Understand the Potential Energy Formula**: The potential energy (\( PE \)) of an electron in a hydrogen-like atom can be expressed in terms of its total energy (\( E \)). The relationship is given by: \[ PE = 2 \times E \] 2. **Total Energy for Hydrogen and Helium Ion**: The total energy (\( E \)) of an electron in a hydrogen-like atom is given by the formula: \[ E = -\frac{13.6 \, Z^2}{n^2} \, \text{eV} \] where \( Z \) is the atomic number and \( n \) is the principal quantum number. 3. **Calculate Total Energy for Hydrogen Atom**: For hydrogen (\( H \)), \( Z = 1 \) and \( n = 2 \): \[ E_H = -\frac{13.6 \times 1^2}{2^2} = -\frac{13.6}{4} = -3.4 \, \text{eV} \] 4. **Calculate Potential Energy for Hydrogen Atom**: Using the relationship \( PE = 2 \times E \): \[ PE_H = 2 \times (-3.4) = -6.8 \, \text{eV} \] 5. **Calculate Total Energy for Helium Ion**: For \( He^{+} \), \( Z = 2 \) and \( n = 2 \): \[ E_{He^+} = -\frac{13.6 \times 2^2}{2^2} = -\frac{13.6 \times 4}{4} = -13.6 \, \text{eV} \] 6. **Calculate Potential Energy for Helium Ion**: Using the relationship \( PE = 2 \times E \): \[ PE_{He^+} = 2 \times (-13.6) = -27.2 \, \text{eV} \] 7. **Calculate the Ratio of Potential Energies**: Now, we can find the ratio of the potential energy of hydrogen to that of helium ion: \[ \text{Ratio} = \frac{PE_H}{PE_{He^+}} = \frac{-6.8}{-27.2} = \frac{6.8}{27.2} = \frac{1}{4} \] ### Final Answer: The ratio of the potential energy of the \( n = 2 \) electron for the hydrogen atom to that of the helium ion is: \[ \frac{1}{4} \]

To solve the problem, we need to find the ratio of the potential energy of the \( n = 2 \) electron for a hydrogen atom (\( H \)) to that of a helium ion (\( He^{+} \)). We will use the Bohr model of the atom to derive the necessary formulas. ### Step-by-Step Solution: 1. **Understand the Potential Energy Formula**: The potential energy (\( PE \)) of an electron in a hydrogen-like atom can be expressed in terms of its total energy (\( E \)). The relationship is given by: \[ PE = 2 \times E ...
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CENGAGE CHEMISTRY ENGLISH-ATOMIC STRUCTURE-Exercises Linked Comprehension
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  2. In a mixture of He^(Theta) gas H atom and He^(Theta) ions Are excited...

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  3. In a mixture of He^(o+) gas H atom and He^(o+) ions Are excited to t...

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  4. In a mixture of He^(o+) gas H atom and He^(o+) ions Are excited to t...

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  5. In a mixture of H - He^(+) gas (He^(+) is singly ionized He atom), H ...

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  6. Consider a system containing a negatively charge point (pi, m(pi) =...

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  7. Consider a system containing a negatively charge point (pi, m(pi) =...

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  8. Consider a system containing a negatively charge poin (pi, m(pi) = ...

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  9. Consider a system containing a negatively charge poin (pi, m(pi) = ...

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  10. A hydrogen like atom (atomic number Z) is in a higher excited state o...

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  11. A hydrogen like atom (atomic number Z) is in a higher excited state o...

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  12. A hydrogen like atom (atomic number Z) is in a higher excited satte ...

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  13. A hydrogen like species (atomic number Z) is present in a higher excit...

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  14. The characteristic X-rays for the lines of K(a) series in element X a...

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  15. The characteristic X-rays for the lines of K(a) series in element X a...

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  16. Werner Heisenberg considered the limits of how precisely we can measur...

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  17. It is impossible to determine simultaneously the position of velocity...

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  18. The seqence of filling electgron in sub-shells of element with few ex...

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  19. If Hund's rule is not obeyed by some element given below then whi...

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  20. The sequence of filling electron in sub-shells of element with few ex...

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