Home
Class 11
CHEMISTRY
A hydrogen like atom (atomic number Z) ...

A hydrogen like atom (atomic number Z) is in a higher excited satte of quantum number n .This excited atom can make a transition to the first excited state by succesively emitting two photon of energies `10.20 eV` and `17.00 eV` .Alternatively, the atom from the same excited state can make a transition to the second excited state by successively emitting twio photon of energy `4.25 ev` and `5.95 eV` Determine the followings:
The atom during transition from `n = 1` to `n = 2` emit radiation in the region of

A

Visible

B

Infira-red

C

UV

D

None

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we need to determine the wavelength of the radiation emitted during the transition from \( n = 1 \) to \( n = 2 \) for a hydrogen-like atom with atomic number \( Z \). ### Step 1: Understand the Energy Levels For a hydrogen-like atom, the energy levels are given by the formula: \[ E_n = -\frac{Z^2 \cdot R}{n^2} \] where \( R \) is the Rydberg constant, approximately \( 13.6 \, \text{eV} \) for hydrogen. ### Step 2: Calculate the Energy Difference To find the energy difference between the levels \( n = 1 \) and \( n = 2 \): \[ E_{1} = -\frac{Z^2 \cdot R}{1^2} = -Z^2 \cdot R \] \[ E_{2} = -\frac{Z^2 \cdot R}{2^2} = -\frac{Z^2 \cdot R}{4} \] The energy difference \( \Delta E \) when transitioning from \( n = 1 \) to \( n = 2 \) is: \[ \Delta E = E_{2} - E_{1} = \left(-\frac{Z^2 \cdot R}{4}\right) - \left(-Z^2 \cdot R\right) = Z^2 \cdot R \left(1 - \frac{1}{4}\right) = Z^2 \cdot R \cdot \frac{3}{4} \] ### Step 3: Calculate the Wavelength Using the energy-wavelength relationship: \[ E = \frac{hc}{\lambda} \] we can rearrange this to find the wavelength \( \lambda \): \[ \lambda = \frac{hc}{E} \] Substituting \( E = Z^2 \cdot R \cdot \frac{3}{4} \): \[ \lambda = \frac{hc}{Z^2 \cdot R \cdot \frac{3}{4}} = \frac{4hc}{3Z^2 \cdot R} \] ### Step 4: Substitute Values Using \( h = 6.626 \times 10^{-34} \, \text{Js} \) and \( c = 3 \times 10^8 \, \text{m/s} \), and \( R = 13.6 \, \text{eV} \) (which we need to convert to Joules by multiplying by \( 1.6 \times 10^{-19} \)): \[ R = 13.6 \, \text{eV} \times 1.6 \times 10^{-19} \, \text{J/eV} = 2.176 \times 10^{-18} \, \text{J} \] Now substituting these values into the wavelength equation: \[ \lambda = \frac{4 \cdot (6.626 \times 10^{-34}) \cdot (3 \times 10^8)}{3Z^2 \cdot (2.176 \times 10^{-18})} \] ### Step 5: Simplify the Expression Calculating the constants: \[ \lambda = \frac{7.9512 \times 10^{-25}}{6.528 \times 10^{-18}Z^2} = \frac{1.216 \times 10^{-7}}{Z^2} \] ### Step 6: Determine the Region of Wavelength The wavelength \( \lambda \) can be converted to nanometers (1 nm = \( 10^{-9} \) m): \[ \lambda = \frac{1.216 \times 10^{-7}}{Z^2} \times 10^9 = \frac{121.6}{Z^2} \, \text{nm} \] ### Conclusion The emitted radiation during the transition from \( n = 1 \) to \( n = 2 \) will be in the ultraviolet region for \( Z > 1 \) since the wavelength will be less than 400 nm.

To solve the problem step by step, we need to determine the wavelength of the radiation emitted during the transition from \( n = 1 \) to \( n = 2 \) for a hydrogen-like atom with atomic number \( Z \). ### Step 1: Understand the Energy Levels For a hydrogen-like atom, the energy levels are given by the formula: \[ E_n = -\frac{Z^2 \cdot R}{n^2} \] where \( R \) is the Rydberg constant, approximately \( 13.6 \, \text{eV} \) for hydrogen. ...
Promotional Banner

Topper's Solved these Questions

  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct|45 Videos
  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct|127 Videos
  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Subjective)|52 Videos
  • APPENDIX - INORGANIC VOLUME 1

    CENGAGE CHEMISTRY ENGLISH|Exercise chapter-7 Single correct answer|1 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|15 Videos

Similar Questions

Explore conceptually related problems

A hydrogen like atom (atomic number z ) is in a higher excited state of quantum number n . This excited atom can make a transition to the first excited state by successively emitting two photons of energies 10.2 eV and 17.0 eV respectively. Alternatively the atom from the same excited state can make a transition to the second excited state by successively emitting 2 photons of energy 4.25 eV and 5.95 eV respectively. Determine the value of (n+z)

A hydrogen like species (atomic number Z) is present in a higher excited state of quantum number n. This excited atom can make a transitionn to the first excited state by successive emission of two photons of energies 10.20 eV and 17.0 eV respectively. Altetnatively, the atom from the same excited state can make a transition to the second excited state by successive of two photons of energy 4.25 eV and 5.95 eVv respectively. Determine the value of Z.

A hydrogen like atom (atomic number Z) is in a higher excited state of quantum number n. The excited atom can make a transition ot the first excited state by successively emitting two photons of energy 10.2 eV and 17.0 eV, respectively. Alternatively, the atom from the same excited state can make a transition to the second excited state by successively emitting two photons of energies 4.25 eV and 5.95 eV, respectivley Determine the values of n and Z. (lonization energy of H-atom = 13.6 eV)

The ratio of the energies of the hydrogen atom in its first to second excited state is

What is covalency of chlorine atom in second excited state ?

What is covalency of chlorine atom in second excited state ?

When a hydrogen atom is excited from ground state to first excited state, then

the energy required to excite an electron in hydrogen atom to its first excited state is

The energy of an atom or ion in the first excited state is -13.6 eV. It may be

The ratio of energies of hydrogen atom in its first excited state to third excited state is

CENGAGE CHEMISTRY ENGLISH-ATOMIC STRUCTURE-Exercises Linked Comprehension
  1. A hydrogen like atom (atomic number Z) is in a higher excited state o...

    Text Solution

    |

  2. A hydrogen like atom (atomic number Z) is in a higher excited state o...

    Text Solution

    |

  3. A hydrogen like atom (atomic number Z) is in a higher excited satte ...

    Text Solution

    |

  4. A hydrogen like species (atomic number Z) is present in a higher excit...

    Text Solution

    |

  5. The characteristic X-rays for the lines of K(a) series in element X a...

    Text Solution

    |

  6. The characteristic X-rays for the lines of K(a) series in element X a...

    Text Solution

    |

  7. Werner Heisenberg considered the limits of how precisely we can measur...

    Text Solution

    |

  8. It is impossible to determine simultaneously the position of velocity...

    Text Solution

    |

  9. The seqence of filling electgron in sub-shells of element with few ex...

    Text Solution

    |

  10. If Hund's rule is not obeyed by some element given below then whi...

    Text Solution

    |

  11. The sequence of filling electron in sub-shells of element with few ex...

    Text Solution

    |

  12. The sequence of filling electron in sub-shells of element with few ex...

    Text Solution

    |

  13. The sepence of filling electgron in sub-shells of element with few ex...

    Text Solution

    |

  14. The only element in the hydrogen atom resides under ordinary conditi...

    Text Solution

    |

  15. The only element in the hydrogen atom resides under ordinary conditi...

    Text Solution

    |

  16. The only element in the hydrogen atom resides under ordinary conditi...

    Text Solution

    |

  17. The only element in the hydrogen atom resides under ordinary conditi...

    Text Solution

    |

  18. The shape of orbitals are related to the ratio of principal quantum ...

    Text Solution

    |

  19. The shape of orbitals are related to the ratio of principal quantum ...

    Text Solution

    |

  20. The shape of orbitals are related to the ratio of principal quantum ...

    Text Solution

    |