Home
Class 11
CHEMISTRY
Which of the following is true ?...

Which of the following is true ?

A

The ionisation energy of a hydrogen -like species in its ground state is equal to the magnitude of energy of the orbit having `n = 1`

B

The ionisation energy of a hydrogen -like species in its ground state increases in principle to the positive charge in its nucleus

C

According to the uncertainty principle `Delta p Delta s le(h)/(4pi)`

D

The energy of an electron in a orbit of a multielectron atom depends only on the principle quantum number n

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question "Which of the following is true?", we need to evaluate each statement regarding hydrogen-like species and atomic structure principles. ### Step-by-Step Solution: 1. **Evaluate the First Statement:** - The ionization energy of a hydrogen-like species in its ground state is equal to the magnitude of energy of the orbit having n = 1. - The ionization energy for hydrogen-like species in the ground state (n=1) is given as 13.6 eV. The energy of the orbit for n=1 is calculated as: \[ E = -\frac{13.6 \, \text{eV}}{n^2} = -\frac{13.6 \, \text{eV}}{1^2} = -13.6 \, \text{eV} \] - The magnitude of this energy is 13.6 eV, which matches the ionization energy. - **Conclusion:** This statement is true. 2. **Evaluate the Second Statement:** - The ionization energy of a hydrogen-like species in its ground state increases in principle to the positive charge in its nucleus. - The ionization energy is given by: \[ E = 13.6 \times \frac{Z^2}{n^2} \] For n=1, it becomes: \[ E = 13.6 \times Z^2 \] - While the ionization energy does depend on Z, it increases with the square of the atomic number (Z^2), not directly with Z. - **Conclusion:** This statement is false. 3. **Evaluate the Third Statement:** - According to the uncertainty principle, \(\Delta p \cdot \Delta x \geq \frac{h}{4\pi}\). - The statement given is incorrect as it states \(\Delta p \cdot \Delta s\) instead of \(\Delta p \cdot \Delta x\). - **Conclusion:** This statement is false. 4. **Evaluate the Fourth Statement:** - The energy of an electron in an orbit of a multi-electron atom depends only on the principal quantum number n. - In multi-electron atoms, the energy also depends on the azimuthal quantum number (l). Therefore, it does not depend solely on n. - **Conclusion:** This statement is false. ### Final Conclusion: Only the first option is true. ---

To solve the question "Which of the following is true?", we need to evaluate each statement regarding hydrogen-like species and atomic structure principles. ### Step-by-Step Solution: 1. **Evaluate the First Statement:** - The ionization energy of a hydrogen-like species in its ground state is equal to the magnitude of energy of the orbit having n = 1. - The ionization energy for hydrogen-like species in the ground state (n=1) is given as 13.6 eV. The energy of the orbit for n=1 is calculated as: \[ ...
Promotional Banner

Topper's Solved these Questions

  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion And Reason|21 Videos
  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer|11 Videos
  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct|45 Videos
  • APPENDIX - INORGANIC VOLUME 1

    CENGAGE CHEMISTRY ENGLISH|Exercise chapter-7 Single correct answer|1 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|15 Videos

Similar Questions

Explore conceptually related problems

Which of the following are true ?

Which of the following are true for Bakelite?

Which of the following are true?

Which of the following are true?

Which of the following are true?

Which of the following are true ?.

Which of the following are true about Mollusca?

Which of the following are true for an acid- base titration?

Which of the following are true for H_(3)PO_(2) ?

Which of the following are true for electrolytic extraction of aluminimum ?