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Which of the following is false?...

Which of the following is false?

A

The energy of an electron in an orbital of a hydrogen -like species depends only on the principle quantum number n

B

The angular momentum of electron in an orbital of a multielectron atom depends on the quantum number l and m

C

The experiment of angular momentum of an orbital is given as `sqrt(l(1 - 1)) ((h)/(2pi))`

D

The z-component of angular momentum of an electron in an orbital is given as `m ((h)/(12pi))`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is false, we will analyze each statement one by one. ### Step 1: Analyze the First Statement **Statement:** The energy of an electron in an orbital of a hydrogen-like species depends only upon the principal quantum number \( n \). **Analysis:** This statement is true. In hydrogen-like species (which have only one electron), the energy levels depend solely on the principal quantum number \( n \). The energy increases as \( n \) increases. **Conclusion:** This statement is true. ### Step 2: Analyze the Second Statement **Statement:** The angular momentum of an electron in an orbital of a multi-electron atom depends upon quantum numbers \( L \) and \( M \). **Analysis:** This statement is also true. The angular momentum in multi-electron systems is determined by the azimuthal quantum number \( L \) and the magnetic quantum number \( M \). **Conclusion:** This statement is true. ### Step 3: Analyze the Third Statement **Statement:** The expression for angular momentum of an orbital is given by \( \sqrt{L(1 - 1)} \frac{h}{2\pi} \). **Analysis:** This statement is false. The correct expression for the orbital angular momentum is given by \( \sqrt{L(L + 1)} \frac{h}{2\pi} \). The formula provided in the statement is incorrect. **Conclusion:** This statement is false. ### Step 4: Analyze the Fourth Statement **Statement:** The \( z \) component of angular momentum of an electron in an orbital is given by \( M \frac{h}{2\pi} \). **Analysis:** This statement is true. The \( z \) component of angular momentum is indeed given by \( M \frac{h}{2\pi} \), where \( M \) is the magnetic quantum number. **Conclusion:** This statement is true. ### Final Conclusion The false statement among the options provided is the third statement regarding the expression for angular momentum. ### Answer: The third statement is false. ---

To determine which statement is false, we will analyze each statement one by one. ### Step 1: Analyze the First Statement **Statement:** The energy of an electron in an orbital of a hydrogen-like species depends only upon the principal quantum number \( n \). **Analysis:** This statement is true. In hydrogen-like species (which have only one electron), the energy levels depend solely on the principal quantum number \( n \). The energy increases as \( n \) increases. **Conclusion:** This statement is true. ...
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