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Assertion (A) : Limiting line is the bal...

Assertion (A) : Limiting line is the balmer series ghas a wavelength of `364.4 nm`
Reason (R ) : Limiting line is obtained for a jump electyron from `n = prop`

A

If both (A) and (R ) correct and (R ) is the correct explanation for (A)

B

If both (A) and (R ) correct and (R ) is the correct explanation for (A)

C

If (A) is correct but (R ) is incorrect

D

If (A) is incorrect but (R ) is correct

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AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the limiting line of the Balmer series has a wavelength of 364.4 nm. - The Balmer series corresponds to electronic transitions in hydrogen where the electron falls to the n=2 energy level from higher energy levels (n=3, 4, 5, ...). 2. **Identifying the Limiting Line**: - The limiting line in the Balmer series occurs when the electron transitions from an infinitely high energy level (n=∞) to the n=2 level. - This transition results in the emission of a photon with a specific wavelength. 3. **Using the Rydberg Formula**: - The Rydberg formula for the wavelength (λ) of the emitted light is given by: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] - For the limiting line of the Balmer series, we set \( n_1 = 2 \) and \( n_2 = \infty \): \[ \frac{1}{\lambda} = R \left( \frac{1}{2^2} - 0 \right) = R \left( \frac{1}{4} \right) \] 4. **Calculating the Wavelength**: - Rearranging gives us: \[ \lambda = \frac{4}{R} \] - The Rydberg constant \( R \) is approximately \( 1.097 \times 10^7 \, \text{m}^{-1} \). - Substituting the value of \( R \): \[ \lambda = \frac{4}{1.097 \times 10^7} \approx 364.4 \, \text{nm} \] - This confirms that the limiting line of the Balmer series indeed corresponds to a wavelength of 364.4 nm. 5. **Understanding the Reason**: - The reason states that the limiting line is obtained for a jump of the electron from \( n = \infty \). - This is correct, as we have established that the limiting line occurs when the electron transitions from an infinitely high energy level to the n=2 level. 6. **Conclusion**: - Both the assertion and the reason are correct. The reason correctly explains the assertion. ### Final Answer: Both the assertion (A) and the reason (R) are correct, and the reason is the correct explanation for the assertion.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the limiting line of the Balmer series has a wavelength of 364.4 nm. - The Balmer series corresponds to electronic transitions in hydrogen where the electron falls to the n=2 energy level from higher energy levels (n=3, 4, 5, ...). ...
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