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Assertion (A) : There are two spherical ...

Assertion (A) : There are two spherical nodes in `3s` orbital
Reason (R ) : There is no planer nodes in `3s` orbital.

A

If both (A) and (R ) correct and (R ) is the correct explanation for (A)

B

If both (A) and (R ) correct and (R ) is not the correct explanation for (A)

C

If (A) is correct but (R ) is incorrect

D

If (A) is incorrect but (R ) is correct

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The correct Answer is:
To solve the assertion and reason question regarding the `3s` orbital, we will follow these steps: ### Step 1: Understand the Assertion The assertion states that there are two spherical nodes in the `3s` orbital. To verify this, we need to use the formula for calculating the total number of nodes in an orbital. ### Step 2: Calculate Total Nodes The total number of nodes in an orbital is given by the formula: \[ \text{Total Nodes} = n - 1 \] where \( n \) is the principal quantum number. For the `3s` orbital: - \( n = 3 \) - Therefore, the total nodes = \( 3 - 1 = 2 \) ### Step 3: Calculate Spherical Nodes The number of spherical nodes is given by the formula: \[ \text{Spherical Nodes} = n - 1 - l \] where \( l \) is the angular momentum quantum number. For the `3s` orbital: - \( s \) corresponds to \( l = 0 \) - Thus, the spherical nodes = \( 3 - 1 - 0 = 2 \) ### Step 4: Conclusion for Assertion Since we calculated that there are indeed 2 spherical nodes in the `3s` orbital, the assertion is **true**. ### Step 5: Understand the Reason The reason states that there are no planar nodes in the `3s` orbital. To verify this, we need to calculate the angular nodes. ### Step 6: Calculate Angular Nodes The number of angular nodes is equal to \( l \). For the `3s` orbital: - \( l = 0 \) - Therefore, the angular nodes = \( 0 \) ### Step 7: Conclusion for Reason Since there are 0 angular nodes, there are also no planar nodes in the `3s` orbital. Thus, the reason is also **true**. ### Step 8: Relationship Between Assertion and Reason While both the assertion and reason are true, the reason does not explain the assertion. The assertion talks about the number of spherical nodes, while the reason discusses planar nodes, which are not directly related. ### Final Conclusion - Assertion (A) is true: There are two spherical nodes in the `3s` orbital. - Reason (R) is true: There are no planar nodes in the `3s` orbital. - However, R is not the correct explanation of A. ### Answer The correct option is: A is true, R is true, but R is not the correct explanation of A. ---

To solve the assertion and reason question regarding the `3s` orbital, we will follow these steps: ### Step 1: Understand the Assertion The assertion states that there are two spherical nodes in the `3s` orbital. To verify this, we need to use the formula for calculating the total number of nodes in an orbital. ### Step 2: Calculate Total Nodes The total number of nodes in an orbital is given by the formula: \[ \text{Total Nodes} = n - 1 \] ...
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