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100 mL of hydrogen was confined in a dif...

`100 mL` of hydrogen was confined in a diffusion tube and exposed to air, and at equilibrium, a volume of `26.1 mL` of air was measured in the tube. Again, when `100 mL` of `CO_(2)` was placed in the same tube and exposed to air, `123 mL` of air was measured in the tube at the equilibrium. Find the molecular weight of `CO_(2)`.

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To solve the problem, we will use Graham's law of diffusion, which states that the rate of diffusion of a gas is inversely proportional to the square root of its molar mass. We will analyze the two cases given in the problem step by step. ### Step 1: Understand the Given Information - In the first case, 100 mL of hydrogen (H₂) was confined in a diffusion tube, and at equilibrium, 26.1 mL of air was measured in the tube. - In the second case, 100 mL of carbon dioxide (CO₂) was placed in the same tube, and at equilibrium, 123 mL of air was measured. ### Step 2: Set Up the Ratios for Graham's Law According to Graham's law, the ratio of the rates of diffusion of two gases is equal to the inverse ratio of the square roots of their molar masses: ...
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CENGAGE CHEMISTRY ENGLISH-STATES OF MATTER-Exercises (Ture False)
  1. 100 mL of hydrogen was confined in a diffusion tube and exposed to air...

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  2. In the van der Waals equation (P + (n^(2)a)/(V^(2)))(V - nb) = nRT ...

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  3. Kinetic energy of a molecule is zero at 0^(@)C

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  4. Gas in a closed container will exert much higher pressure due to gravi...

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  5. The graph between PV vs P at constant temperature is linear parallel t...

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  6. Real gases show deviation from ideal behavior at low temperature and h...

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  7. All the molecules in a given sample of gas move with same speed.

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  8. Small value of a means, gas can be easily liqueifed.

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  9. Small value of a means, gas can be easily liqueifed.

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  10. Rate of diffusion is directly proportional to the square root of molec...

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  11. For ideal gases, Z = 1 at all temperature and pressure.

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  12. According to charles's law,

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  13. The pressure of moist gas is higher than pressure of dry gas.

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  14. Gases do not occupy volume and do not have force of attraction.

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  15. The van der Waal equation of gas is (P + (n^(2)a)/(V^(2))) (V - nb)...

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  16. Surface tension and surface energy have different dimensions.

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  17. The plot of PV vs P at particular temperature is called isovbar.

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  18. Give reasons for the following in one or two sentences. (a) A bottle...

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  19. Can a gas with a = 0 be liquefied?

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  20. The van der waals constants have same values for all the gases.

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  21. All the molecules in a given sample of gas move with same speed.

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