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1 mol of C Cl(4) vapours at 77^(@)C occu...

`1 mol` of `C Cl_(4)` vapours at `77^(@)C` occupies a volume of `35.0 L`. If van der Waals constants are `a=20.39 L^(2) atm mol^(-2)` and `b=0.1383 L mol^(-1)`, calculate compressibility factor `Z` under
(`a`) Low pressure region
(`b`) High pressure region

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AI Generated Solution

To calculate the compressibility factor \( Z \) for \( 1 \, \text{mol} \) of \( \text{CCl}_4 \) vapors at \( 77^\circ C \) occupying a volume of \( 35.0 \, \text{L} \) under low and high pressure regions, we can follow these steps: ### Given Data: - Number of moles, \( n = 1 \, \text{mol} \) - Volume, \( V = 35.0 \, \text{L} \) - Temperature, \( T = 77^\circ C = 350 \, \text{K} \) (convert to Kelvin by adding 273) - Van der Waals constants: - \( a = 20.39 \, \text{L}^2 \, \text{atm} \, \text{mol}^{-2} \) ...
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CENGAGE CHEMISTRY ENGLISH-STATES OF MATTER-Exercises (Ture False)
  1. 1 mol of C Cl(4) vapours at 77^(@)C occupies a volume of 35.0 L. If va...

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  2. In the van der Waals equation (P + (n^(2)a)/(V^(2)))(V - nb) = nRT ...

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  3. Kinetic energy of a molecule is zero at 0^(@)C

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  4. Gas in a closed container will exert much higher pressure due to gravi...

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  5. The graph between PV vs P at constant temperature is linear parallel t...

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  6. Real gases show deviation from ideal behavior at low temperature and h...

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  7. All the molecules in a given sample of gas move with same speed.

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  8. Small value of a means, gas can be easily liqueifed.

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  9. Small value of a means, gas can be easily liqueifed.

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  10. Rate of diffusion is directly proportional to the square root of molec...

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  11. For ideal gases, Z = 1 at all temperature and pressure.

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  12. According to charles's law,

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  13. The pressure of moist gas is higher than pressure of dry gas.

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  14. Gases do not occupy volume and do not have force of attraction.

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  15. The van der Waal equation of gas is (P + (n^(2)a)/(V^(2))) (V - nb)...

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  16. Surface tension and surface energy have different dimensions.

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  17. The plot of PV vs P at particular temperature is called isovbar.

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  18. Give reasons for the following in one or two sentences. (a) A bottle...

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  19. Can a gas with a = 0 be liquefied?

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  20. The van der waals constants have same values for all the gases.

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  21. All the molecules in a given sample of gas move with same speed.

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