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Assertion: C(P)-C(V)=R for an ideal gas....

Assertion: `C_(P)-C_(V)=R` for an ideal gas.
Reason: `((delE)/(delV))_(T)=0` for an ideal gas.

A

If both (`A`) and (`R`) are correct and (`R`) is the correct explanation of (`A`).

B

If both (`A`) and (`R`) are correct, but (`R`) is not the correct explanation of (`A`).

C

If (`A`) is correct, but (`R`) is incorrect.

D

If (`A`) is incorrect, but (`R`) is correct.

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To solve the given assertion and reason question, we will break it down step by step. ### Step 1: Understand the Assertion The assertion states that \( C_P - C_V = R \) for an ideal gas. - **Explanation**: - \( C_P \) is the molar heat capacity at constant pressure. - \( C_V \) is the molar heat capacity at constant volume. - \( R \) is the universal gas constant. ### Step 2: Derive the Relationship To derive the relationship \( C_P - C_V = R \): 1. Start with the definition of enthalpy (\( H \)): \[ H = U + PV \] where \( U \) is the internal energy. 2. The change in enthalpy at constant pressure is given by: \[ dH = nC_P dT \] 3. The change in internal energy is given by: \[ dU = nC_V dT \] 4. The differential form of enthalpy can also be expressed as: \[ dH = dU + d(PV) \] 5. From the ideal gas equation, we know: \[ PV = nRT \implies d(PV) = nRdT \] 6. Substitute \( dU \) and \( d(PV) \) into the enthalpy equation: \[ dH = nC_V dT + nRdT \] 7. Equating the two expressions for \( dH \): \[ nC_P dT = nC_V dT + nRdT \] 8. Dividing through by \( n dT \) (assuming \( dT \neq 0 \)): \[ C_P = C_V + R \] 9. Rearranging gives: \[ C_P - C_V = R \] ### Step 3: Understand the Reason The reason states that \( \left( \frac{\partial E}{\partial V} \right)_T = 0 \) for an ideal gas. - **Explanation**: - This means that the change in internal energy \( E \) with respect to volume \( V \) at constant temperature \( T \) is zero. ### Step 4: Analyze the Reason 1. For an ideal gas, the internal energy \( U \) depends only on temperature, not on volume or pressure. 2. Therefore, at constant temperature, any change in volume does not affect the internal energy: \[ \left( \frac{\partial U}{\partial V} \right)_T = 0 \] 3. This implies that the internal energy remains constant with changes in volume at constant temperature. ### Step 5: Conclusion Both the assertion and reason are correct statements. However, they are not directly related to each other. The assertion discusses the relationship between heat capacities, while the reason discusses the behavior of internal energy with volume at constant temperature. ### Final Answer The correct answer is **B**: Both Assertion and Reason are correct, but Reason is not the correct explanation for Assertion. ---

To solve the given assertion and reason question, we will break it down step by step. ### Step 1: Understand the Assertion The assertion states that \( C_P - C_V = R \) for an ideal gas. - **Explanation**: - \( C_P \) is the molar heat capacity at constant pressure. - \( C_V \) is the molar heat capacity at constant volume. ...
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CENGAGE CHEMISTRY ENGLISH-STATES OF MATTER-Exercises (Assertion-Reasoning)
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  2. Assertion: The pressure of a fixed amount of an ideal gas is proportio...

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  3. Assertion: C(P)-C(V)=R for an ideal gas. Reason: ((delE)/(delV))(T)=...

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  4. Assertion: A lighter gas diffuses more rapidly than heavier gas. Rea...

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  5. Assertion: On cooling, the brown colour of nitrogen dioxide disappears...

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  6. Assertion (A): SO(2) and Cl(2) are both bleaching agents. Reason (R ...

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  7. Assertion: Nitrogen is unreactive at room temperature but becomes reac...

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  8. Assertion: Noble gases can be liquefied. Reason: Attractive forces c...

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  9. Assertion: Under similar conditions of temperature and pressure,O(2) d...

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  10. Assertion: On compressing a gas to half the volume, the number of mole...

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  11. Assertion: The plot of volume (V) versus pressure (P) at constant temp...

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  12. Assertion: At constant temperature, if pressure on the gas is doubled,...

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  13. Assertion: If H(2) and Cl enclosed separately in the same vessel exert...

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  14. STATEMENT-1 : Most probable speed is the speed possessed by maximum fr...

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  15. Assertion: Compressibility factor (Z) for non ideal gases is always gr...

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  16. Assertion: van der Waals equation is applicable only to non-ideal gase...

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  17. STATEMENT-1 : Helium shows only positive deviation from ideal behaviou...

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  18. Assertion: Gases are easily adsorbed on the surface of metals, especia...

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  19. Assertion: SO(2) gas is easily liquefied while H(2) is not. Reason: ...

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  20. Assertion: Molecules of air in a room do not all fall and settle on th...

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