Home
Class 11
CHEMISTRY
The values of DeltaH and DeltaS for two ...

The values of `DeltaH` and `DeltaS` for two reactions are given below:
Reaction `A : DeltaH =- 10.0 xx 10^(3)J mol^(-1)`
`DeltaS = +30 J K^(-1) mol^(-1)`
Reaction `B: DeltaH =- 11.0 xx 10^(3)J mol^(-1)`
`DeltaS =- 100J K^(-1) mol^(-1)`
Decide whether these reactions are spontaneous or not at `300K`.

Text Solution

AI Generated Solution

To determine whether the reactions A and B are spontaneous at 300 K, we need to calculate the Gibbs free energy change (ΔG) for each reaction using the formula: \[ \Delta G = \Delta H - T \Delta S \] where: - ΔG is the change in Gibbs free energy, ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Subjective)|70 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Paragraph for Problem|1 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 6.4|16 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

From the following values of DeltaH and DeltaS , decide whether or not these reaction are feasible at 298 K. Reaction A : DeltaH =- 10.5 xx 10^3 J mol^(-1), DeltaS = + 31J K^(-1) mol^(-1) Reaction B : DeltaH = - 11.7 xx 10^3 J mol^(-1), DeltaS = - 105 J K^(-1) mol^(-1)

A+BtoC+D DeltaH=-10,000 J mol^(-1) DeltaS-33.3 J mol^(-1)K^(-1) At what temperature the reaction will occur spontaneous from left to right ?

For A rarr B, DeltaH= 3.5 kcal mol^(-1), DeltaS= 10 cal mol^(-1) K^(-1) . Reaction is non spontaneous at

Rate constant of two reactions are given below. Identifying their order of reaction k = 5.3 xx 10^(-2) L mol^(-1) s^(-1) k = 3.8 xx 10^(-4) s^(-1)

For a reaction at 25^(@)C enthalpy change (DeltaH) and entropy change (DeltaS) are -11.7 K J mol^(-1) and -105J mol^(-1) K^(-1) , respectively. Find out whether this reaction is spontaneous or not?

For a reaction at 25^(@)C enthalpy change (DeltaH) and entropy change (DeltsS) are -11.7 K J mol^(-1) and -105J mol^(-1) K^(-1) , respectively. Find out whther this reaction is spontaneous or not?

Following are the values of E_(a) and DeltaH for three reactions carried out at the same temperature : I :E_(a)=20kJ mol^(-1),DeltaH=-60kJmol^(-1) II :E_(a)=10kJ mol^(-1),DeltaH=-20kJ mol^(-1) III : E_(a)=40 kJ mol^(-1),DeltaH=+15kJ mol^(-1) If all the three reaction have same frequency factor then fastest and slowest reaction are :

For a given reaction, DeltaH = 35.5 kJ mol^(-1) and Delta S = 83.6 JK^(-1) mol^(-1) . The reaction is spontaneous at (Assume that DeltaH and DeltaS do not vary with temperature)

A process has DeltaH=200Jmol^(-1) and DeltaS=40JK^(-1)mol^(-1) . The minimum temperature above which the process will be spontaneous is ___________K.

The free energy for a reaction having DeltaH=31400 cal, DeltaS=32" cal "K^(-1)mol^(-1) at 1000^(@)C is:

CENGAGE CHEMISTRY ENGLISH-THERMODYNAMICS-Ex 6.5
  1. Calculated the Gibbs energy change on dissolving one mole of sodium ch...

    Text Solution

    |

  2. The values of DeltaH and DeltaS for two reactions are given below: R...

    Text Solution

    |

  3. Calculate the temperature above which the reaction of lead oxide to le...

    Text Solution

    |

  4. For the reaction, N(2)(g) +3H(2)(g) rarr 2NH(3)(g) DeltaH =- 95.0 ...

    Text Solution

    |

  5. Enthalpy and entropy changes of reaction are 40.63 kJ mol^(-1) and 108...

    Text Solution

    |

  6. Predict whether it is possible or not to reduce magnesium oxide using ...

    Text Solution

    |

  7. The standard Gibbs energy change value (Delta(r)G^(Theta)) at 1773K ar...

    Text Solution

    |

  8. In a fuel cell, methanol if used as fuel and oxygen gas is used as an ...

    Text Solution

    |

  9. On the basic of the following Delta(r)G^(Theta) values at 1073K: S(1...

    Text Solution

    |

  10. Consider the reaction: 4NH(3)(g) +5O(2)(g) rarr 4NO(g) +6H(2)O(l) De...

    Text Solution

    |

  11. Calculate the standard Gibbs free energy change from the free energies...

    Text Solution

    |

  12. Consider the reaction: 2NO(g)+O(2)(g) rarr 2NO(2)(g) Calculated th...

    Text Solution

    |

  13. For the water gas reaction, C(s) +H(2)O(g) hArr CO(g)+H(2)(g) the ...

    Text Solution

    |

  14. Using the following data, calculate the value of equilibrium constant ...

    Text Solution

    |

  15. The equilibrium constant at 25^(@)C for the process: CO^(3+) (aq) +6...

    Text Solution

    |

  16. The standard Gibbs energies (Delta(f)G^(Theta)) for the formation of S...

    Text Solution

    |

  17. It is planned to carry out the reaction: CaCO(3)(s) hArr CaO(s) +CO(...

    Text Solution

    |

  18. The equilibrium constant for the reaction CO(2)(g) +H(2)(g) hArr CO(...

    Text Solution

    |

  19. Calculated the equilibrium constant for the following reaction at 298K...

    Text Solution

    |

  20. The equilibrium constant for the reaction: CH(3)COOH(l) +C(2)H(5)OH(...

    Text Solution

    |