Home
Class 11
CHEMISTRY
On the basic of the following Delta(r)G^...

On the basic of the following `Delta_(r)G^(Theta)` values at `1073K`:
`S_(1)(s) +2O_(2)(g) rarr 2SO_(2)(g) Delta_(r)G^(Theta) =- 544 kJ mol^(-1)`
`2Zn(s) +O_(2)(g) rarr 2ZnO(s) Delta_(r)G^(Theta) =- 480 kJ mol^(-1)`
`2Zn(s) +S_(2)(s) rarr 2ZnS(s) Delta_(r)G^(Theta) =- 293 KJ mol^(-1)`
Show that roasting of zinc sulphide to zince oxide is a spontaneous process.

Text Solution

AI Generated Solution

To show that the roasting of zinc sulfide (ZnS) to zinc oxide (ZnO) is a spontaneous process, we need to calculate the change in Gibbs free energy (ΔG) for the reaction and check if it is negative. The roasting reaction can be represented as: \[ 2 \text{ZnS}(s) + 3 \text{O}_2(g) \rightarrow 2 \text{ZnO}(s) + 2 \text{SO}_2(g) \] ### Step 1: Identify the Reactions and Their ΔG Values We have the following reactions and their corresponding ΔG values at 1073 K: 1. \( \text{S}_1(s) + 2 \text{O}_2(g) \rightarrow 2 \text{SO}_2(g) \) ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Subjective)|70 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Paragraph for Problem|1 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 6.4|16 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

For the system S (s) + O_(2)(g) rarr SO_(2)(g) ?

The standard Gibbs energy change value (Delta_(r)G^(Theta)) at 1773K are given for the following reactions: 4Fe +3O_(2) rarr 2Fe_(2)O_(3), Delta_(r)G^(Theta) = - 1487 kJ mol^(-1) 4AI +3O_(2) rarr 2AI_(2)O_(3),Delta_(r)G^(Theta) =- 22500 kJ mol^(-1) 2CO +O_(2) rarr 2CO_(2),Delta_(r)G^(Theta) =- 515 kJ mol^(-1) Find out the possibility of reducing Fe_(2)O_(3) and AI_(2)O_(3) with CO at this temperature.

Comment on the thermodynamic stability of NO(g) , given 1/2N_(2)(g)+1/2O_(2)(g)rarr NO(g), Delta_(r)H^(Θ)=90 kJ mol^(-1) NO(g)+1/2O_(2)(g) rarr NO_(2)(g), Delta_(r)H^(Θ)=-74 kJ mol^(-1)

Consider the reaction: 4NH_(3)(g) +5O_(2)(g) rarr 4NO(g) +6H_(2)O(l) DeltaG^(Theta) =- 1010.5 kJ Calculate Delta_(f)G^(Theta) [NO(g)] if Delta_(f)G^(Theta) (NH_(3)) = -16.6 kJ mol^(-1) and Delta_(f)G^(Theta) [H_(2)O(l)] =- 237.2 kJ mol^(-1) .

From the data at 25^(@)C : Fe_(2)O_(3)(s) +3C_(("graphite")) rarr 2Fe(s) + 3CO(g), DeltaH^(Theta) = 492.0 kJ mol^(-1) FeO(s) +C_(("graphite")) rarr Fe(s) CO(g), DeltaH^(Theta) = 155.0 kJ mol^(-1) C_(("graphite")) +O_(2)(g) rarr CO_(2)(g), DeltaH^(Theta) =- 393.0 kJ mol^(-1) CO(g)+(1)/(2)O_(2)(g) rarr CO_(2)(g), DeltaH^(Theta) =- 282.0 kJ mol^(-1) Calculate the standard heat of formation of FeO(s) and Fe_(2)O_(3)(s) .

At 1000^(@)C , Zn_((s)) +(1)/(2)O_(2(g)) to ZnO_((s)), DeltaG^(@)=-360 KJ "mol"^(-1) C_((s)) + (1)/(2)O_(2(g)) to CO_((g)),DeltaG^(@) =-460 KJ "mol"^(-1) The correct statement is

Using the following thermochemical equations : S("rhombic") + 3/2 O_(2)(g) rarr SO_(3)(g), " "Delta H = - 2x kJ mol^(-1) II. SO_(2)(g) + 1/2 O_(2)(g) rarr SO_(3)(g), " "Delta H = -Y kJ mol^(-1) Find out the heat of formation of SO_(2)(g) in kJ mol^(-1) .

Calculate enthalpy of formation of methane (CH_4) from the following data : (i) C(s) + O_(2)(g) to CO_(2) (g) , Delta_rH^(@) = -393.5 KJ mol^(-1) (ii) H_2(g) + 1/2 O_(2)(g) to H_(2)O(l) , Deta_r H^(@) = -285.5 kJ mol^(-1) (iii) CH_(4)(g) + 2O_(2)(g) to CO_(2)(g) + 2H_(2)O(l), Delta_(r)H^(@) = -890.3 kJ mol^(-1) .

Methanol can be prepared synthetically by heating carbon monoxide and hydrogen gases under pressure in the presence of a catalyst. The reaction is CO(g) +2H_(2)(g) rarr CH_(3)OH(l) Determine the enthalpy of this reaction by an appropriate combinantion of the following data: a. C_(("graphite")) +(1)/(2)O_(2)(g) rarr CO(g), DeltaH^(Theta)=- 110.5kJ mol^(-1) b. C_(("graphite")) +O_(2)(g) rarr CO_(2)(g), DeltaH^(Theta) =- 393.5 kJ mol^(-1) c. H_(2)(g) +(1)/(2)O_(2)(g) rarr H_(2)O(l), DeltaH^(Theta) =- 285.9kJ mol^(-1) d. CH_(3)OH(l) +(3)/(2)O_(2)(g)rarr CO_(2)(g) +2H_(2)O(l),DeltaH^(Theta) =- 726.6 kJ mol^(-1)

Given: i. 2Fe(s) +(3)/(2)O_(2)(g) rarr Fe_(2)O_(3)(s), DeltaH^(Theta) =- 193.4 kJ ii. Mg(s) +(1)/(2)O_(2)(g) rarr MgO(s), DeltaH^(Theta) =- 140.2kJ What is DeltaH^(Theta) of the reaction? 3Mg +Fe_(2)O_(3)rarr 3MgO +2Fe

CENGAGE CHEMISTRY ENGLISH-THERMODYNAMICS-Ex 6.5
  1. The standard Gibbs energy change value (Delta(r)G^(Theta)) at 1773K ar...

    Text Solution

    |

  2. In a fuel cell, methanol if used as fuel and oxygen gas is used as an ...

    Text Solution

    |

  3. On the basic of the following Delta(r)G^(Theta) values at 1073K: S(1...

    Text Solution

    |

  4. Consider the reaction: 4NH(3)(g) +5O(2)(g) rarr 4NO(g) +6H(2)O(l) De...

    Text Solution

    |

  5. Calculate the standard Gibbs free energy change from the free energies...

    Text Solution

    |

  6. Consider the reaction: 2NO(g)+O(2)(g) rarr 2NO(2)(g) Calculated th...

    Text Solution

    |

  7. For the water gas reaction, C(s) +H(2)O(g) hArr CO(g)+H(2)(g) the ...

    Text Solution

    |

  8. Using the following data, calculate the value of equilibrium constant ...

    Text Solution

    |

  9. The equilibrium constant at 25^(@)C for the process: CO^(3+) (aq) +6...

    Text Solution

    |

  10. The standard Gibbs energies (Delta(f)G^(Theta)) for the formation of S...

    Text Solution

    |

  11. It is planned to carry out the reaction: CaCO(3)(s) hArr CaO(s) +CO(...

    Text Solution

    |

  12. The equilibrium constant for the reaction CO(2)(g) +H(2)(g) hArr CO(...

    Text Solution

    |

  13. Calculated the equilibrium constant for the following reaction at 298K...

    Text Solution

    |

  14. The equilibrium constant for the reaction: CH(3)COOH(l) +C(2)H(5)OH(...

    Text Solution

    |

  15. Calculate the entropy change for a reaction: XrarrY Given that Del...

    Text Solution

    |

  16. Calculate the equilibrium constant for the following reaction at 298K ...

    Text Solution

    |

  17. For the equilibrium reaction: 2H(2)(g) +O(2)(g) hArr 2H(2)O(l) at 29...

    Text Solution

    |

  18. Calculate equilibrium constant for the reaction given below at 400K, i...

    Text Solution

    |

  19. Calculate equilibrium constant for the reaction: 2SO(2)(g) +O(2)(g) ...

    Text Solution

    |

  20. C(2)H(4) +CI(2) rarr C(2)H(4)CI(2) DeltaH =- 270.6 kJ mol^(-1)K^(-1)...

    Text Solution

    |