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Bond energies can be obtained by using t...

Bond energies can be obtained by using the following relation: `DeltaH (reaction) = sum`Bond energy of bonds, broken in the reactants `-sum` Bond energy fo bonds, formed in the products
Bond enegry depends on three factors:
a. Greater is the bond length, lesser is the bond enegry.
b. Bond energy increases with the bond multiplicity.
c. Bond enegry increases with electronegativity difference between the bonding atoms.
Use the bond enegries to estimate `DeltaH` for this reaction:
`H_(2)(g) +O_(2)(g) rarr H_(2)O_(2)(g)`
`{:("Bond","Bond energy"),(H-H,436 kJ mol^(-1)),(O-O,142 kJ mol^(-1)),(O=O, 499kJ mol^(-1)),(H-O,460kJ mol^(-1)):}`

A

`-127 kJ`

B

`-109 kJ`

C

`-400 kJ`

D

`-800 kJ`

Text Solution

AI Generated Solution

To estimate the change in enthalpy (ΔH) for the reaction \( H_2(g) + O_2(g) \rightarrow H_2O_2(g) \) using bond energies, we can follow these steps: ### Step 1: Identify the bonds broken in the reactants In the reaction, we have: - One \( H-H \) bond in \( H_2 \) - One \( O=O \) bond in \( O_2 \) ### Step 2: Identify the bonds formed in the products ...
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CENGAGE CHEMISTRY ENGLISH-THERMODYNAMICS-Exercises (Linked Comprehension)
  1. Bond energies can be obtained by using the following relation: DeltaH ...

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  2. Bond energies can be obtained by using the following relation: DeltaH ...

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  3. Bond energies can be obtained by using the following relation: DeltaH ...

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  4. Bond energies can be obtained by using the following relation: DeltaH ...

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  5. A change in the free energy of a system at constant temperature and pr...

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  6. A change in the free energy of a system at constant temperature and pr...

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  7. A change in the free energy of a system at constant temperature and pr...

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  8. A change in the free energy of a system at constant temperature and pr...

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  9. Identify the correct statement for change of Gibbs free energy for a s...

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  10. Process A rarr B represents

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  11. The pressure at C is

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  12. Work done in the process C rarrA is

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  13. The process which occurs in going from B rarr C is

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  14. The pressures at A and B in the atmosphere are, respectively,

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  15. The thermodynamic property that measures the extent of molecular disor...

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  16. The thermodynamic property that measures the extent of molecular disor...

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  17. The thermodynamic property that measures the extent of molecular disor...

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  18. For which of the following cases, DeltaS = (DeltaH)/(T)?

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  19. The thermodynamic property that measures the extent of molecular disor...

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  20. The pressure-volume of varies thermodynamic process is shown in graphs...

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