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Assertion (A): Heat of neutralisation fo...

Assertion (A): Heat of neutralisation for both `HNO_(3)` and `HCI` with `NaOH` is `53.7 kJ per mol^(-1)`.
Reason (R ) : `NaOH` is a strong electrolyte/base.

A

If both (A) and (R ) are correct, and (R ) is the correct explanation for (A).

B

If the both (A) and (R ) are correct, but(R ) is not a correct explanation for (A).

C

If (A) is correct, but (R ) is incorrect.

D

If (A) is incorrect, but (R ) is correct.

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To solve the given assertion and reason question, we will analyze both statements and determine their validity. ### Step 1: Understand the Assertion The assertion states that the heat of neutralization for both HNO₃ (nitric acid) and HCl (hydrochloric acid) with NaOH (sodium hydroxide) is 53.7 kJ per mol. **Explanation**: - The heat of neutralization is the amount of heat released when an acid reacts with a base to form water and a salt. - For strong acids (like HCl and HNO₃) reacting with a strong base (like NaOH), the heat of neutralization is typically around 57.1 kJ/mol. However, the value of 53.7 kJ/mol is often cited in literature, accounting for slight variations in experimental conditions. ...
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Assertion : Heat of neutralisation of HNO_(3) and NaOH is same as that of HCl and KOH. Reason : Both HNO_(3) and HCl are storng acids and NaOH and KOH are strong bases.

The heat of neutralisation of HCI with NaOH is same as that of HNO_(3) with KOH .

Assertion : The heat of neutralisation for a strong acid and a weak base is always equal to -57.1 kJ. Reason : One gram equivalent of a strong acid always neutralises one gram equivalent of a weak base.

Explain why heat of neutralisation of strong acid and weak base is less than 57.1 kJ .

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