Home
Class 11
CHEMISTRY
Assertion (A): The Heat of ionisation o...

Assertion (A): The Heat of ionisation of water is equal to the heat of neutralistion of a strong acid with a strong base.
Reason (R ) : Water ionises to a very small extent while `H^(o+)` ions from from an acid combine very rapidly with `overset(Theta)OH` from a base to form `H_(2)O`.

A

If both (A) and (R ) are correct, and (R ) is the correct explanation for (A).

B

If the both (A) and (R ) are correct, but(R ) is not a correct explanation for (A).

C

If (A) is correct, but (R ) is incorrect.

D

If (A) is incorrect, but (R ) is correct.

Text Solution

AI Generated Solution

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the heat of ionization of water is equal to the heat of neutralization of a strong acid with a strong base. - Ionization of water refers to the process where water dissociates into hydrogen ions (H⁺) and hydroxide ions (OH⁻). - Neutralization is the reaction between an acid (which produces H⁺ ions) and a base (which provides OH⁻ ions) to form water. ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Interger)|10 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Fill In The Blanks)|52 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Single Correct)|62 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

The heat of neutralisation for strong acid and strong base forming 2 moles of water is

The enthalpy of formation of H_(2)O(l) is -280.70 kJ/mol and enthalpy of neutralisation of a strong acid and strong base is -56.70 kJ/mol. What is the enthalpy of formation of OH^(-) ions?

The enthalpy of formation of H_(2)O(l) is -285 KJ mol^(-1) and enthalpy of neutralization of a stron acid and a strong bas is -55 KJ mol^(-1) . What is the enthalpy of formation of OH^(-) ions?

The enthalpy of formation of H_(2)O(l) is -285 KJ mol^(-1) and enthalpy of neutralization of a stron acid and a strong bas is -55 KJ mol^(-1) . What is the enthalpy of formation of OH^(-) ions?

Assertion(A) : The value of enthalpy of neutralization of a weak acid by strong base is numerically less than 57.1 kJ . Reason(R ) : All OH^(-) ions of strong base are not completely neutralized by H^(+) ions obtained from acid.

If water is formed from H^(+) ions and OH^(-) the heat of formation of water is :

Assertion : The heat of neutralisation for a strong acid and a weak base is always equal to -57.1 kJ. Reason : One gram equivalent of a strong acid always neutralises one gram equivalent of a weak base.

Assertion (A): BaCO_(3) is more soluble in HNO_(3) than in water. Reason (R ): Carbonate is a weak base and reacts with H^(o+) ions to form strong acid causing barium salt to dissociate.

Assertion (A): When small amount of acid or base is added to pure water, its pH undergoes a change. Reason (R) : Addition of an acid or a basic increases the degree of ionisation of water.

Assertion : Weak acids have very strong conjugate bases while strong acids have weak conjugate bases. Reason : Conjugate acid - base pair differ only by one proton.

CENGAGE CHEMISTRY ENGLISH-THERMODYNAMICS-Exercises (Assertion-Reasoning)
  1. Assertion (A): The thermodynamic factor which determines the spontane...

    Text Solution

    |

  2. Assertion (A): The Joules -Thomon coefficient for an ideal gas is zer...

    Text Solution

    |

  3. Assertion (A): Enthalpy of graphite is lower than that of diamond. R...

    Text Solution

    |

  4. Assertion: The enthalpy of formation of gaseous oxygen molecules at 29...

    Text Solution

    |

  5. Assertion (A): Heat of neutralisation for both HNO(3) and HCI with NaO...

    Text Solution

    |

  6. Assertion (A): Decrease in free energy causes spontaneous reaction ...

    Text Solution

    |

  7. Many endothermic reactions that are not spontaneous at room temperatur...

    Text Solution

    |

  8. Assertion (A): The enthalpy of formation of H(2)O(l) is greater than t...

    Text Solution

    |

  9. Assertion (A): For a particular reaction, heat of combustion at consta...

    Text Solution

    |

  10. Assertion (A): The enthalpy of both graphite and diamond is taken to ...

    Text Solution

    |

  11. Assertion (A): The heat of neutralisation of perchloric acid, HCIO(4),...

    Text Solution

    |

  12. Assertion (A): The Heat of ionisation of water is equal to the heat o...

    Text Solution

    |

  13. Assertion (A): The enthalpy of formation of HCI is equal to the bond e...

    Text Solution

    |

  14. Assertion (A): Pressure, volume, and temperature are all extensive pro...

    Text Solution

    |

  15. Assertion (A): When a gas at high pressure expands against vacuum, th...

    Text Solution

    |

  16. Assertion: When a real gas is allowed to expand adiabatically through ...

    Text Solution

    |

  17. Assertion : There is no change in internal energ in a cyclic process. ...

    Text Solution

    |

  18. Assertion (A): An exothermic process, non-spontaneous at high temperat...

    Text Solution

    |

  19. Assertion (A): There is no reaction known for which DeltaG is positive...

    Text Solution

    |

  20. A reaction which is spontaneous and accompanied by decrease of randomn...

    Text Solution

    |