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For A+BhArrC+D , the equilibrium constan...

For `A+BhArrC+D` , the equilibrium constant is `K_(1)` and for `C+DhArrA+B`, the equilibrium constant is `K_(2)`. The correct relation between `K_(1)` and `K_(2)` is

A

`K_(1)xxK_(2)=1`

B

`K_(1)xx(K_(2)-1)=0`

C

`K_(1)//K_(2)=1`

D

All of these

Text Solution

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The correct Answer is:
To solve the problem, we need to analyze the two given chemical reactions and their equilibrium constants. ### Step-by-Step Solution: 1. **Identify the Reactions and Their Equilibrium Constants**: - The first reaction is: \[ A + B \rightleftharpoons C + D \] The equilibrium constant for this reaction is denoted as \( K_1 \). - The second reaction is: \[ C + D \rightleftharpoons A + B \] The equilibrium constant for this reaction is denoted as \( K_2 \). 2. **Write the Expression for \( K_1 \)**: - The equilibrium constant \( K_1 \) for the first reaction can be expressed as: \[ K_1 = \frac{[C][D]}{[A][B]} \] where \([C]\), \([D]\), \([A]\), and \([B]\) are the molar concentrations of the respective substances at equilibrium. 3. **Write the Expression for \( K_2 \)**: - The equilibrium constant \( K_2 \) for the second reaction can be expressed as: \[ K_2 = \frac{[A][B]}{[C][D]} \] 4. **Relate \( K_1 \) and \( K_2 \)**: - Notice that the expression for \( K_2 \) is the inverse of the expression for \( K_1 \): \[ K_2 = \frac{1}{K_1} \] - This implies: \[ K_1 K_2 = 1 \] 5. **Conclusion**: - The correct relation between \( K_1 \) and \( K_2 \) is: \[ K_1 K_2 = 1 \quad \text{or} \quad K_1 = \frac{1}{K_2} \] ### Final Answer: The correct relation between \( K_1 \) and \( K_2 \) is \( K_1 K_2 = 1 \).

To solve the problem, we need to analyze the two given chemical reactions and their equilibrium constants. ### Step-by-Step Solution: 1. **Identify the Reactions and Their Equilibrium Constants**: - The first reaction is: \[ A + B \rightleftharpoons C + D ...
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