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When 4 mol of A is mixed with 4 mol of B...

When `4 mol` of `A` is mixed with `4 mol` of `B, 2 mol` of `C` and `D` are formed at equilibrium, according to the reaction
`A+B hArr C+D`
the equilibrium constant is

A

(a) `sqrt(2)`

B

(b) `2`

C

(c) `1`

D

(d) `4`

Text Solution

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To find the equilibrium constant \( K \) for the reaction \( A + B \rightleftharpoons C + D \), we can follow these steps: ### Step 1: Write the balanced chemical equation The balanced equation for the reaction is: \[ A + B \rightleftharpoons C + D \] ### Step 2: Identify the initial moles of reactants We are given: - Initial moles of \( A = 4 \, \text{mol} \) - Initial moles of \( B = 4 \, \text{mol} \) ### Step 3: Identify the moles of products at equilibrium At equilibrium, we are told that: - Moles of \( C = 2 \, \text{mol} \) - Moles of \( D = 2 \, \text{mol} \) ### Step 4: Determine the change in moles of reactants Since 2 moles of \( C \) and 2 moles of \( D \) are formed, we can determine the change in moles of \( A \) and \( B \): - Moles of \( A \) remaining = Initial moles of \( A \) - Moles of \( C \) formed \[ \text{Moles of } A = 4 - 2 = 2 \, \text{mol} \] - Moles of \( B \) remaining = Initial moles of \( B \) - Moles of \( D \) formed \[ \text{Moles of } B = 4 - 2 = 2 \, \text{mol} \] ### Step 5: Write the expression for the equilibrium constant \( K \) The equilibrium constant \( K \) is defined as: \[ K = \frac{[\text{C}]^c [\text{D}]^d}{[\text{A}]^a [\text{B}]^b} \] For our reaction, where \( a = b = c = d = 1 \): \[ K = \frac{[C][D]}{[A][B]} \] ### Step 6: Substitute the equilibrium concentrations Assuming the volume of the reaction vessel is \( V \), the concentrations at equilibrium are: - \([C] = \frac{2}{V}\) - \([D] = \frac{2}{V}\) - \([A] = \frac{2}{V}\) - \([B] = \frac{2}{V}\) Substituting these values into the expression for \( K \): \[ K = \frac{\left(\frac{2}{V}\right) \left(\frac{2}{V}\right)}{\left(\frac{2}{V}\right) \left(\frac{2}{V}\right)} = \frac{\frac{4}{V^2}}{\frac{4}{V^2}} = 1 \] ### Step 7: Conclusion Thus, the equilibrium constant \( K \) for the reaction is: \[ K = 1 \] ---

To find the equilibrium constant \( K \) for the reaction \( A + B \rightleftharpoons C + D \), we can follow these steps: ### Step 1: Write the balanced chemical equation The balanced equation for the reaction is: \[ A + B \rightleftharpoons C + D \] ...
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