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If N(2)+3H(2)overset(K)(hArr)2NH(3) the...

If `N_(2)+3H_(2)overset(K)(hArr)2NH_(3)` then `2N_(2)+6H_(2)overset(K')(hArr)4NH_(3);K'` is equal to

A

`K^(2)`

B

`(K)^(1//3)`

C

`1//sqrt(K)`

D

`1//K^(2)`

Text Solution

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The correct Answer is:
To find the relationship between the equilibrium constants \( K \) and \( K' \) for the given reactions, we can follow these steps: ### Step 1: Write the first reaction and its equilibrium constant. The first reaction is: \[ N_2 + 3H_2 \rightleftharpoons 2NH_3 \] The equilibrium constant \( K \) for this reaction is given by: \[ K = \frac{[NH_3]^2}{[N_2][H_2]^3} \] ### Step 2: Write the second reaction and its equilibrium constant. The second reaction is: \[ 2N_2 + 6H_2 \rightleftharpoons 4NH_3 \] We need to express the equilibrium constant \( K' \) for this reaction. ### Step 3: Write the expression for \( K' \). The equilibrium constant \( K' \) for the second reaction is given by: \[ K' = \frac{[NH_3]^4}{[N_2]^2[H_2]^6} \] ### Step 4: Relate \( K' \) to \( K \). Notice that the second reaction is essentially the first reaction multiplied by 2. When we multiply a balanced chemical equation by a factor, the equilibrium constant is raised to the power of that factor. Therefore, since we multiplied the first reaction by 2, we can relate \( K' \) to \( K \) as follows: \[ K' = K^2 \] ### Conclusion Thus, the relationship between the equilibrium constants is: \[ K' = K^2 \]

To find the relationship between the equilibrium constants \( K \) and \( K' \) for the given reactions, we can follow these steps: ### Step 1: Write the first reaction and its equilibrium constant. The first reaction is: \[ N_2 + 3H_2 \rightleftharpoons 2NH_3 \] The equilibrium constant \( K \) for this reaction is given by: ...
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