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Equilibrium constants (K) for the reacti...

Equilibrium constants `(K)` for the reaction `2NO(g)+Cl_(2)(g)hArr2NOCl(g)` is correctly given by the expression

A

(a) `([NOCl]^(2))/([NO]^(2)[Cl_(2)])`

B

(b) `([2NOCl])/([2NO][Cl_(2)])`

C

(c) `([NO]^(2)+[Cl_(2)])/([NOCl])`

D

(d) `([NO]^(2)[Cl_(2)])/([NOCl]^(2))`

Text Solution

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The correct Answer is:
To derive the equilibrium constant expression for the reaction \(2NO(g) + Cl_2(g) \rightleftharpoons 2NOCl(g)\), we will follow these steps: ### Step 1: Write the balanced chemical equation The balanced chemical equation is: \[ 2NO(g) + Cl_2(g) \rightleftharpoons 2NOCl(g) \] ### Step 2: Identify the products and reactants In the equation, the reactants are \(2NO\) and \(Cl_2\), and the product is \(2NOCl\). ### Step 3: Write the general form of the equilibrium constant expression The equilibrium constant \(K\) is expressed in terms of the concentrations of the products and reactants. The general form is: \[ K = \frac{[\text{products}]^{\text{stoichiometric coefficient}}}{[\text{reactants}]^{\text{stoichiometric coefficient}}} \] ### Step 4: Apply the stoichiometric coefficients For our specific reaction: - The product \(NOCl\) has a stoichiometric coefficient of 2. - The reactant \(NO\) has a stoichiometric coefficient of 2. - The reactant \(Cl_2\) has a stoichiometric coefficient of 1. ### Step 5: Write the equilibrium constant expression Substituting the products and reactants into the general form, we get: \[ K = \frac{[NOCl]^2}{[NO]^2 \cdot [Cl_2]^1} \] ### Step 6: Finalize the expression Thus, the equilibrium constant expression for the reaction is: \[ K = \frac{[NOCl]^2}{[NO]^2 \cdot [Cl_2]} \] ### Conclusion The correct expression for the equilibrium constant \(K\) for the reaction \(2NO(g) + Cl_2(g) \rightleftharpoons 2NOCl(g)\) is: \[ K = \frac{[NOCl]^2}{[NO]^2 \cdot [Cl_2]} \] ---

To derive the equilibrium constant expression for the reaction \(2NO(g) + Cl_2(g) \rightleftharpoons 2NOCl(g)\), we will follow these steps: ### Step 1: Write the balanced chemical equation The balanced chemical equation is: \[ 2NO(g) + Cl_2(g) \rightleftharpoons 2NOCl(g) \] ### Step 2: Identify the products and reactants In the equation, the reactants are \(2NO\) and \(Cl_2\), and the product is \(2NOCl\). ...
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