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For an ideal gas reaction 2A+BhArrC+D ...

For an ideal gas reaction
`2A+BhArrC+D`
the value of `K_(p)` will be:

A

`K_(p)=(n_(C )n_(D))/(n_(A)^(2)n_(B)).V/(RT^(2))`

B

`K_(p)=(n_(C )n_(D))/(n_(A)^(2)n_(B)).V/(RT)`

C

`K_(p)=(n_(C )n_(D))/(n_(A)^(2)n_(B)).(RT)/V`

D

`K_(p)=(n_(C )n_(D))/(4n_(A)^(2)n_(B)).V/(RT)`

Text Solution

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The correct Answer is:
To find the value of \( K_p \) for the reaction \( 2A + B \rightleftharpoons C + D \), we can follow these steps: ### Step 1: Write the expression for \( K_p \) For a general reaction of the form \( aA + bB \rightleftharpoons cC + dD \), the equilibrium constant \( K_p \) is given by: \[ K_p = \frac{(P_C)^c (P_D)^d}{(P_A)^a (P_B)^b} \] For our specific reaction \( 2A + B \rightleftharpoons C + D \), this becomes: \[ K_p = \frac{(P_C)^1 (P_D)^1}{(P_A)^2 (P_B)^1} \] ### Step 2: Relate partial pressures to concentrations Using the ideal gas law, \( PV = nRT \), we can express the partial pressures in terms of concentrations. The partial pressure \( P \) of a gas can be expressed as: \[ P = \frac{n}{V}RT \] where \( n \) is the number of moles, \( V \) is the volume, and \( R \) is the ideal gas constant. Therefore, we can write: \[ P_A = \frac{n_A}{V}RT, \quad P_B = \frac{n_B}{V}RT, \quad P_C = \frac{n_C}{V}RT, \quad P_D = \frac{n_D}{V}RT \] ### Step 3: Substitute the expressions into the \( K_p \) formula Substituting these expressions into the \( K_p \) formula gives: \[ K_p = \frac{\left(\frac{n_C}{V}RT\right)^1 \left(\frac{n_D}{V}RT\right)^1}{\left(\frac{n_A}{V}RT\right)^2 \left(\frac{n_B}{V}RT\right)^1} \] ### Step 4: Simplify the expression This simplifies to: \[ K_p = \frac{(n_C)(n_D)(RT)^2}{(n_A)^2(n_B)(V^2)(RT)^2} \] The \( (RT)^2 \) terms cancel out, leading to: \[ K_p = \frac{n_C n_D}{n_A^2 n_B} \cdot \frac{1}{V^2} \] ### Step 5: Final expression for \( K_p \) Thus, we can express \( K_p \) as: \[ K_p = \frac{n_C n_D}{n_A^2 n_B} \cdot \frac{1}{V^2} \] ### Conclusion The final expression for \( K_p \) for the reaction \( 2A + B \rightleftharpoons C + D \) is: \[ K_p = \frac{n_C n_D}{n_A^2 n_B} \cdot \frac{1}{V^2} \]

To find the value of \( K_p \) for the reaction \( 2A + B \rightleftharpoons C + D \), we can follow these steps: ### Step 1: Write the expression for \( K_p \) For a general reaction of the form \( aA + bB \rightleftharpoons cC + dD \), the equilibrium constant \( K_p \) is given by: \[ K_p = \frac{(P_C)^c (P_D)^d}{(P_A)^a (P_B)^b} ...
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