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Which of the following relation(s) holds...

Which of the following relation(s) holds good for gaseous and reversible reactions?

A

`K_(p)/K_(c )=(RT)^((Deltan)_(g))`

B

`K_(p)/K_(c)=(P)^((Deltan)_(g))`

C

`K_(c )/K_(p)=(p/(RT))^((Deltan)_(g))`

D

`K_(c )/K_(p)=(P)^(-(Deltan)_(g))`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the relations that hold good for gaseous and reversible reactions, we will analyze the relationships between the equilibrium constants \( K_p \) and \( K_c \). ### Step-by-Step Solution: 1. **Understanding the Definitions**: - \( K_p \) is the equilibrium constant for gaseous reactions expressed in terms of partial pressures. - \( K_c \) is the equilibrium constant for gaseous reactions expressed in terms of molar concentrations. 2. **Relation Between \( K_p \) and \( K_c \)**: - For a gaseous reversible reaction, the relationship between \( K_p \) and \( K_c \) is given by the formula: \[ K_p = K_c \cdot (RT)^{\Delta n_g} \] - Here, \( R \) is the universal gas constant, \( T \) is the temperature in Kelvin, and \( \Delta n_g \) is the change in the number of moles of gas, calculated as: \[ \Delta n_g = \text{(moles of gaseous products)} - \text{(moles of gaseous reactants)} \] 3. **Rearranging the Equation**: - Rearranging the equation \( K_p = K_c \cdot (RT)^{\Delta n_g} \) gives us: \[ \frac{K_p}{K_c} = (RT)^{\Delta n_g} \] - This matches with the first option provided in the question. 4. **Evaluating Other Options**: - The second option \( \frac{K_p}{K_c} = P^{\Delta n_g} \) is incorrect as it does not include the \( RT \) term. - The third option \( \frac{K_c}{K_p} = \frac{P}{RT}^{\Delta n_g} \) is also incorrect as it does not reflect the correct relationship. - The fourth option \( \frac{K_c}{K_p} = P^{-\Delta n_g} \) is incorrect for the same reason. 5. **Conclusion**: - The only correct relation that holds good for gaseous and reversible reactions is: \[ \frac{K_p}{K_c} = (RT)^{\Delta n_g} \] - Therefore, the correct answer is **Option 1**.

To solve the question regarding the relations that hold good for gaseous and reversible reactions, we will analyze the relationships between the equilibrium constants \( K_p \) and \( K_c \). ### Step-by-Step Solution: 1. **Understanding the Definitions**: - \( K_p \) is the equilibrium constant for gaseous reactions expressed in terms of partial pressures. - \( K_c \) is the equilibrium constant for gaseous reactions expressed in terms of molar concentrations. ...
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