Home
Class 11
CHEMISTRY
The activation energy of H(2)+I(2) hAr...

The activation energy of
`H_(2)+I_(2) hArr 2HI(g)` in equilibrium for the forward reaction is `167 kJ mol^(-1)` whereas for the reverse reaction is `180 kJ mol^(-1)`. The presence of catalyst lowers the activation energy by `80 kJ mol^(-1)`. Assuming that the reactions are made at `27^(@)C` and the frequency factor for forwatd and backward reactions are `4xx10^(-4)` and `2xx10^(-3)` respectively, calculate `K_(c)`.

Text Solution

AI Generated Solution

To solve the problem, we will follow these steps: ### Step 1: Determine the new activation energies for both reactions The activation energy for the forward reaction is given as 167 kJ/mol. The presence of a catalyst lowers this by 80 kJ/mol. \[ \text{New Activation Energy for Forward Reaction (E_a1)} = 167 \, \text{kJ/mol} - 80 \, \text{kJ/mol} = 87 \, \text{kJ/mol} \] ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Concept Applicationexercise 7.1|53 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 7.2|40 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|15 Videos
  • CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Analytical and Descriptive Type|3 Videos

Similar Questions

Explore conceptually related problems

The activation energy for the forward reaction X rarr Y is 60 kJ mol^(-1) and Delta H is -20 kJ mol^(-1) . The activation energy for the reverse reaction is

The activation energy of a first order reaction at 300 K is 60 kJ mol^(-1) . In the presence of a catalyst, the activation energy gets lowered to 50kJ mol^(-1) at 300 K . How many times the reaction rate change in the presence of a catalyst at the same temperature ?

The energy of activation for a reaction is 100 KJ mol^(-1) . The peresence of a catalyst lowers the energy of activation by 75% . What will be the effect on the rate of reaction at 20^(@)C , other things being equal?

The activation energy for most of the reaction is approximately 50 kJ mol^(-1) . The rate for temperature coefficient for such reaction will be

The activation energy of exothermic reaction ArarrB is 80 kJ "mol"^(-1) . The heat of reaction is 200 kJ "mol"^(-1) . The activation energy for the reaction Brarra ( in kJ/mol) will be :

K_(p) for a reaction at 25^(@)C is 10 atm. The activation energy for forward and reverse reactions are 12 and 20 kJ mol^(-1) respectively. The K_(c) for the reaction at 40^(@)C will be:

In an exothermic reaction X rarr Y , the activation energy is 100 kJ mol^(-1) of X . The enthalphy of the reaction is -140 kJ mol^(-1) . The activation energy of the reverse reaction Y rarr X is