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In the preparation of CaO from CaCO(3) u...

In the preparation of CaO from `CaCO_(3)` using the equilibrium,
`CaCO_(3)(s) hArr CaO(s)+CO_(2)(g)`
`K_(p)` is expressed as
`log K_(p)=7.282-8500/T`
For complete decomposition of `CaCO_(3)`, the temperature in celsius to be used is:

A

`1167`

B

`894`

C

`8500`

D

`850`

Text Solution

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The correct Answer is:
To solve the problem of finding the temperature in Celsius required for the complete decomposition of calcium carbonate (CaCO₃) into calcium oxide (CaO) and carbon dioxide (CO₂), we will follow these steps: ### Step-by-Step Solution: 1. **Understand the Reaction and Kp**: The equilibrium reaction is: \[ \text{CaCO}_3(s) \rightleftharpoons \text{CaO}(s) + \text{CO}_2(g) \] The expression for \( K_p \) is given as: \[ \log K_p = 7.282 - \frac{8500}{T} \] 2. **Condition for Complete Decomposition**: For complete decomposition of CaCO₃, we need \( K_p = 1 \). This is because at complete decomposition, the partial pressures of the products and reactants reach a certain equilibrium where they balance out. 3. **Set Up the Equation**: Since \( K_p = 1 \), we know: \[ \log K_p = \log 1 = 0 \] Therefore, we can set up the equation: \[ 0 = 7.282 - \frac{8500}{T} \] 4. **Solve for T**: Rearranging the equation gives: \[ \frac{8500}{T} = 7.282 \] Now, solving for \( T \): \[ T = \frac{8500}{7.282} \] Calculating this gives: \[ T \approx 1167.26 \text{ K} \] 5. **Convert Temperature to Celsius**: To convert the temperature from Kelvin to Celsius, use the formula: \[ T(°C) = T(K) - 273.15 \] Substituting the value of \( T \): \[ T(°C) = 1167.26 - 273.15 \approx 894.11 °C \] 6. **Final Answer**: The temperature required for the complete decomposition of CaCO₃ into CaO and CO₂ is approximately: \[ \boxed{894.11 °C} \]

To solve the problem of finding the temperature in Celsius required for the complete decomposition of calcium carbonate (CaCO₃) into calcium oxide (CaO) and carbon dioxide (CO₂), we will follow these steps: ### Step-by-Step Solution: 1. **Understand the Reaction and Kp**: The equilibrium reaction is: \[ \text{CaCO}_3(s) \rightleftharpoons \text{CaO}(s) + \text{CO}_2(g) ...
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