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The exothermic formation of ClF(3) is re...

The exothermic formation of `ClF_(3)` is represented by thr equation:
`Cl_(2)(g)+3F_(2)(g) hArr 2ClF_(3)(g), DeltaH=-329 kJ`
Which of the following will increase the quantity of `ClF_(3)` in an equilibrium mixture of `Cl_(2), F_(2)`, and `ClF_(3)`?

A

Increasing the temperature

B

Removing `Cl_(2)`

C

Increasing the volume of the container

D

Adding `F_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given equilibrium reaction and how changes in conditions affect the quantity of the product, ClF₃. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction given is: \[ \text{Cl}_2(g) + 3\text{F}_2(g) \rightleftharpoons 2\text{ClF}_3(g) \] This is an exothermic reaction with a change in enthalpy (\(\Delta H\)) of -329 kJ. 2. **Understand Le Chatelier's Principle**: According to Le Chatelier's principle, if a system at equilibrium is subjected to a change in concentration, temperature, or pressure, the equilibrium will shift to counteract that change. 3. **Analyze the Changes**: We want to increase the quantity of ClF₃ in the equilibrium mixture. To do this, we can: - Increase the concentration of reactants (Cl₂ or F₂). - Decrease the concentration of products (ClF₃). - Change the temperature or pressure, but in this case, we focus on concentration changes. 4. **Consider the Options**: The question asks which of the following will increase the quantity of ClF₃. The most effective way to shift the equilibrium to the right (towards the products) is to increase the concentration of the reactants. 5. **Adding F₂**: If we add more F₂ to the system, the equilibrium will shift to the right to consume the added F₂, resulting in the formation of more ClF₃. This is because more F₂ will react with Cl₂ to produce ClF₃. 6. **Conclusion**: Therefore, the action that will increase the quantity of ClF₃ in the equilibrium mixture is the addition of F₂. ### Final Answer: Adding more F₂ will increase the quantity of ClF₃ in the equilibrium mixture. ---

To solve the problem, we need to analyze the given equilibrium reaction and how changes in conditions affect the quantity of the product, ClF₃. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction given is: \[ \text{Cl}_2(g) + 3\text{F}_2(g) \rightleftharpoons 2\text{ClF}_3(g) \] ...
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