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At 500 K, the equilibrium constant for r...

At `500 K`, the equilibrium constant for reaction `cis-C_(2)H_(2)Cl_(2) hArr transa-C_(2)H_(2)Cl_(2)` is `0.6`. At the same temperature, the equilibrium constant for the reaction `trans-C_(2)H_(2)Cl_(2) hArr cis-C_(2)H_(2)Cl_(2)` will be

A

`1.67`

B

`1.65`

C

`1.06`

D

`1.60`

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The correct Answer is:
To solve the problem, we need to determine the equilibrium constant for the reaction where trans-C₂H₂Cl₂ is converted to cis-C₂H₂Cl₂, given that the equilibrium constant for the reverse reaction is provided. ### Step-by-Step Solution: 1. **Identify the Given Information:** - The equilibrium constant for the reaction: \[ \text{cis-C}_2\text{H}_2\text{Cl}_2 \rightleftharpoons \text{trans-C}_2\text{H}_2\text{Cl}_2 \] is given as \( K_1 = 0.6 \) at \( 500 \, K \). 2. **Understand the Relationship Between the Reactions:** - The reverse reaction is: \[ \text{trans-C}_2\text{H}_2\text{Cl}_2 \rightleftharpoons \text{cis-C}_2\text{H}_2\text{Cl}_2 \] - The equilibrium constant for the reverse reaction, \( K_2 \), is related to \( K_1 \) by the following relationship: \[ K_2 = \frac{1}{K_1} \] 3. **Calculate the Equilibrium Constant for the Reverse Reaction:** - Substitute the value of \( K_1 \) into the equation: \[ K_2 = \frac{1}{0.6} \] - Perform the calculation: \[ K_2 = \frac{1}{0.6} = 1.6667 \] 4. **Round the Result:** - Rounding \( 1.6667 \) gives us \( 1.67 \). 5. **Final Answer:** - Therefore, the equilibrium constant \( K_2 \) for the reaction trans-C₂H₂Cl₂ to cis-C₂H₂Cl₂ is approximately \( 1.67 \). ### Conclusion: The equilibrium constant for the reaction \( \text{trans-C}_2\text{H}_2\text{Cl}_2 \rightleftharpoons \text{cis-C}_2\text{H}_2\text{Cl}_2 \) is \( K_2 = 1.67 \).
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL EQUILIBRIUM-Concept Applicationexercise 7.1
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  2. In the reversible reaction, 2HI(g) hArr H(2)(g)+I(2)(g), K(p) is

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  3. At 500 K, the equilibrium constant for reaction cis-C(2)H(2)Cl(2) hArr...

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  4. 2 mol of N(2) is mixed with 6 mol of H(2) in a closed vessel of one li...

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  5. For the reaction H(2)(g)+CO(2) (g)hArrCO(g)+H(2)O(g), if the initial ...

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  6. Partial pressure of O(2) in the reaction 2Ag(2)O(s) hArr 4Ag(s)+O(2)...

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  7. Two moles of PCl(5) were heated to 327^(@)C in a closed two-litre vess...

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  8. For the reaction, 2NO2 (g) hArr 2NO(g) +O2(g), (Kc= 1.8 xx 10...

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  9. For a reaction NH(4)COONH(4(s))hArr2NH(3(g))+CO(2(g)), the equilibrium...

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  10. For the reaction A+B hArr C+D, the initial concentrations of A and B a...

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  11. 15 mol of H(2) and 5.2 moles of I(2) are mixed and allowed to attain e...

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  12. For the reaction: 2NOCl(g) hArr 2NO(g) +Cl(2)(g), K(c) at 427^(@)C is ...

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  13. For the reaction CuSO(4).5H(2)O(s) hArr CuSO(4).3H(2)O(s)+2H(2)O(g) ...

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  14. Which one is the correct representation for the reaction 2SO(2)(g)+O...

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  15. For the reactions, CO(g) +Cl2( g) hArr COCl2(g), " the " (KP)/(Kc...

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  16. The equilibrium constant for the reacction N(2)(g)+O(2)(g)hArr2NO(g) a...

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  17. K(p)//K(c) for the reaction CO(g)+1/2 O(2)(g) hArr CO(2)(g) is

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  18. The unit of equilibrium constant K(c) for the reaction A+B hArr C woul...

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  19. For which of the following reaction does the equilibrium constant depe...

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  20. To the system, LaCl(3)(s)+H(2)O(g) hArr LaClO(s)+2HCL(g)-"Heat" alre...

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