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N(2)O(2) hArr 2NO, K(1), (1/2)N(2)+(1/...

`N_(2)O_(2) hArr 2NO, K_(1),`
`(1/2)N_(2)+(1/2)O_(2) hArr NO, K_(2),`
`2NO hArr N_(2)+O_(2),K_(3),`
`NO hArr (1/2)N_(2)+(1/2)O_(2),K_(4)`
Correct relaton(s) between `K_(1), K_(2), K_(3)` and `K_(4)` is/are

A

`K_(1)xxK_(3)=1`

B

`sqrt(K_(1))xxK_(4)=1`

C

`sqrt(K_(3))xxK_(2)=1`

D

None

Text Solution

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The correct Answer is:
A, B, C
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K_(1) and K_(2) are equilibrium constants for reaction (i) and (ii) N_(2)(g)+O_(2)(g) hArr 2NO(g) …(i) NO(g) hArr 1//2 N_(2)(g)+1//2O_(2)(g) …(ii) then,

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CENGAGE CHEMISTRY ENGLISH-CHEMICAL EQUILIBRIUM-Exercises (Multiple Correct)
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  3. The reaction which proceeds in the backward direction is

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  4. For which of the following reaction, K(p) ne K(c)?

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  5. Select the incorrect statements:

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  6. For the chemical reaction 3X(g)+Y(g) hArr X(3)Y(g), the amount of ...

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  7. When two reactants A and B are mixed to give products C and D, the rea...

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  8. At constant temperature , the equilibrium constant (KP) for the deco...

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  9. Consider the following equilibrium in a closed container, N(2)O(4(g)...

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  10. Which of the following do not change the value of K for a reaction?

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  11. For which of the following reactions at equilibrium at constant temper...

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  12. Unit of equilibrium constant is:

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  13. Which is/are correct?

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  14. For the reaction, CaCO(3)(s) rarr CaO(s)+CO(2)(g), which is the correc...

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  15. N(2)O(2) hArr 2NO, K(1), (1/2)N(2)+(1/2)O(2) hArr NO, K(2), 2NO hA...

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  16. The rate of disappearance of A at two temperature is given by A hArr B...

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  17. Which of the following factors would favour the formation of ammonia?

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  18. Which of the following will not affect the value of equilibrium consta...

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  19. Which of the following statement is/are wrong?

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  20. When NaNO(3) is heated in a closed vessel, oxygen is liberated and NaN...

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