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Assertion (A) : Equilibrium constant of ...

Assertion (A) : Equilibrium constant of a reaction increases if temperature is increased
Reason (R) : The forward reaction becomes faster with increase of temperature.

A

If both (A) and (R) are correct, and (R) is the correct explanation for (A)

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A)

C

If (A) is correct, but (R) is incorrect

D

If (A) is incorrect, but (R) is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion and reason question regarding the equilibrium constant and temperature, we will analyze both the assertion (A) and the reason (R) step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the equilibrium constant (Kc) of a reaction increases if the temperature is increased. - The relationship between the equilibrium constant and temperature is described by the Van 't Hoff equation: \[ \log K_c = -\frac{\Delta H}{2.303 R} \left(\frac{1}{T}\right) + \text{constant} \] - Here, \(\Delta H\) is the change in enthalpy of the reaction, and R is the universal gas constant. 2. **Analyzing the Effect of Temperature**: - If \(\Delta H > 0\) (endothermic reaction), increasing temperature (T) leads to an increase in Kc. - If \(\Delta H < 0\) (exothermic reaction), increasing temperature leads to a decrease in Kc. - Therefore, the assertion that Kc increases with temperature is **not universally true**; it depends on whether the reaction is endothermic or exothermic. 3. **Conclusion on Assertion (A)**: - The assertion is **false** because it does not hold true for exothermic reactions. 4. **Understanding the Reason (R)**: - The reason states that the forward reaction becomes faster with an increase in temperature. - According to the Arrhenius equation: \[ k = A e^{-\frac{E_a}{RT}} \] - Here, \(k\) is the rate constant, \(A\) is the pre-exponential factor, \(E_a\) is the activation energy, and \(T\) is the temperature. - As temperature increases, the term \(-\frac{E_a}{RT}\) becomes less negative, leading to an increase in the rate constant \(k\). 5. **Conclusion on Reason (R)**: - The reason is **true** because an increase in temperature generally increases the rate of the forward reaction. 6. **Final Conclusion**: - Since the assertion (A) is false and the reason (R) is true, the correct answer is that **A is incorrect but R is correct**.

To solve the assertion and reason question regarding the equilibrium constant and temperature, we will analyze both the assertion (A) and the reason (R) step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the equilibrium constant (Kc) of a reaction increases if the temperature is increased. - The relationship between the equilibrium constant and temperature is described by the Van 't Hoff equation: \[ ...
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