Home
Class 11
CHEMISTRY
Assertion (A) : When a catalyst is added...

Assertion (A) : When a catalyst is added to a reaction mixture in equilibrium the amount of the products increases.
Reason (R) : The forward reaction becomes faster on adding the catalyst.

A

If both (A) and (R) are correct, and (R) is the correct explanation for (A)

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A)

C

If (A) is correct, but (R) is incorrect

D

If (A) is incorrect, but (R) is correct.

Text Solution

AI Generated Solution

The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding the Assertion (A):** The assertion states that when a catalyst is added to a reaction mixture at equilibrium, the amount of products increases. This implies that the presence of a catalyst affects the concentrations of reactants and products at equilibrium. 2. **Analyzing the Role of a Catalyst:** A catalyst is a substance that increases the rate of a chemical reaction without being consumed in the process. It does this by providing an alternative reaction pathway with a lower activation energy. However, it does not change the position of the equilibrium or the concentrations of reactants and products at equilibrium. 3. **Understanding the Equilibrium Concept:** In a chemical equilibrium, the rates of the forward and reverse reactions are equal, and the concentrations of reactants and products remain constant. The addition of a catalyst speeds up both the forward and reverse reactions equally, but it does not favor one direction over the other. 4. **Conclusion on Assertion (A):** Since a catalyst does not change the concentrations of reactants or products at equilibrium, the assertion that the amount of products increases when a catalyst is added is **incorrect**. 5. **Understanding the Reason (R):** The reason states that the forward reaction becomes faster upon adding a catalyst. This is true because a catalyst lowers the activation energy for the forward reaction, allowing it to proceed more quickly. 6. **Conclusion on Reason (R):** While the reason is correct, it does not support the assertion. The increase in the rate of the forward reaction does not lead to an increase in the amount of products at equilibrium. 7. **Final Evaluation:** - Assertion (A) is **false**. - Reason (R) is **true**. - Therefore, the correct answer is that the assertion is incorrect while the reason is correct.

**Step-by-Step Solution:** 1. **Understanding the Assertion (A):** The assertion states that when a catalyst is added to a reaction mixture at equilibrium, the amount of products increases. This implies that the presence of a catalyst affects the concentrations of reactants and products at equilibrium. 2. **Analyzing the Role of a Catalyst:** A catalyst is a substance that increases the rate of a chemical reaction without being consumed in the process. It does this by providing an alternative reaction pathway with a lower activation energy. However, it does not change the position of the equilibrium or the concentrations of reactants and products at equilibrium. ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Integer)|7 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Fill In The Blanks)|35 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Single Correct)|58 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|15 Videos
  • CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Analytical and Descriptive Type|3 Videos

Similar Questions

Explore conceptually related problems

Assertion (A) : Equilibrium constant of a reaction increases if temperature is increased Reason (R) : The forward reaction becomes faster with increase of temperature.

When NaCl is added to the reaction mixture of an oil and caustic soda, the soap is thrown out because

A catalyst increases the rate of a reaction by:

When a catalyst increases the rate of chemical reaction the rate constant :-

Assertion (A) : If the activation energy of a reaction is zero, temperature will have no effect on the rate constant. Reason (R ): Lower the activation energy, faster is the reaction.

A catalyst increases the rate of a chemical reaction by

Assertion (A) : The rate of a chemical reaction whether exothermic or endothermic increases with temperature. Reason (R ): The rate reaction =k["Reactant"]^(n) and k increases with temperature.

Assertion (A): Poistive catalyst lowers the activation energy of the reaction whereas the heat of reaction remains same. Reason (R ): The heat of reaction is equal to the difference between activation energies for forward and backward reactions.

A catalyst increases the rate of forward reaction and decrease the rate of backwark reaction.

Assertion (A) : A catalyst does not influences the values of equilibrium constant Reason (R) : Catalyst influences the rate of both forward and backward reactions equally.