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Assertion (A) : For the reaction H(2)+...

Assertion (A) : For the reaction
`H_(2)+I_(2) hArr 2HI, K_(p)=K_(c)`
Reason (R) : In this reaction, the sum of stoichiometric coefficient of reactants is equal to the sum of stoichiometric coefficients of products.

A

If both (A) and (R) are correct, and (R) is the correct explanation for (A)

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A)

C

If (A) is correct, but (R) is incorrect

D

If (A) is incorrect, but (R) is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided. ### Step-by-step Solution: 1. **Understanding the Reaction**: The reaction given is: \[ H_2 + I_2 \rightleftharpoons 2HI \] Here, we have 1 mole of \(H_2\) and 1 mole of \(I_2\) as reactants, and 2 moles of \(HI\) as products. 2. **Assertion Analysis**: The assertion states that for this reaction, \(K_p = K_c\). To verify this, we need to understand the relationship between \(K_p\) and \(K_c\): \[ K_p = K_c (RT)^{\Delta n} \] where \(\Delta n\) is the change in the number of moles of gas, calculated as the moles of products minus the moles of reactants. 3. **Calculating \(\Delta n\)**: - **Products**: 2 moles of \(HI\) - **Reactants**: 1 mole of \(H_2\) + 1 mole of \(I_2\) = 2 moles - Therefore, \(\Delta n = n_{products} - n_{reactants} = 2 - 2 = 0\). 4. **Substituting \(\Delta n\) into the \(K_p\) and \(K_c\) relationship**: Since \(\Delta n = 0\), we can substitute this into the equation: \[ K_p = K_c (RT)^0 = K_c \cdot 1 = K_c \] Hence, the assertion \(K_p = K_c\) is true. 5. **Reason Analysis**: The reason states that in this reaction, the sum of the stoichiometric coefficients of reactants is equal to the sum of the stoichiometric coefficients of products. - The sum of stoichiometric coefficients for reactants: \(1 (H_2) + 1 (I_2) = 2\) - The sum of stoichiometric coefficients for products: \(2 (HI) = 2\) - Since both sums are equal, the reason is also true. 6. **Conclusion**: Both the assertion and the reason are correct, and the reason correctly explains the assertion because the equality of the stoichiometric coefficients leads to \(\Delta n = 0\), which in turn leads to \(K_p = K_c\). ### Final Answer: Both assertion (A) and reason (R) are correct, and R is the correct explanation of A. ---
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