Home
Class 11
CHEMISTRY
Consider a buffer solution containing 0....

Consider a buffer solution containing `0.1mol` each of acetic and sodium acetate in `1.0L` of solution, `0.01mol` of `NaOH` is gradually added to this buffer solution. Calculate the average buffer capacity of the solution and as well as initial and final buffer capacity. `[K_(a) = 2 xx 10^(-5)] pK_(a) = 4.7`

Text Solution

AI Generated Solution

To solve the problem, we will follow these steps: ### Step 1: Calculate Initial pH of the Buffer Solution We start with a buffer solution containing 0.1 mol of acetic acid (CH₃COOH) and 0.1 mol of sodium acetate (CH₃COONa) in 1 L of solution. Using the Henderson-Hasselbalch equation: \[ \text{pH} = \text{pKa} + \log\left(\frac{[\text{Salt}]}{[\text{Acid}]}\right) ...
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 8.1|18 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 8.2|27 Videos
  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective Archive (Subjective)|3 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY ENGLISH|Exercise Assertion-Reasoning Type|1 Videos

Similar Questions

Explore conceptually related problems

When 0.1 mole of an acid is added to 2 L of a buffer solution, the P^(H) of the buffer decreases by 0.5 . The buffer capacity of the solution is

When 0.002mol of acid is added to 250 mL of a buffer solution, pH decreases by 0.02 units. The buffer capacity of the system is

A buffer solution contains 0.15 moles of acetic acid and 0.20 moles of potassium acetate per litre. The dissociation constant of acetic acid at room temperature is 1.76×10^(−5) Calculate the pH of the solution.

A buffer solution contains 0.1 mole of sodium acetate dissolved in 1000cm^(3) of 0.1 M acetic acid. To the above buffer solution, 0.1 mole of sodium acetate is further added and dissolved. The pH of the resulting buffer is :

When 0.01 moles of NaOH are added to 1 litre of a buffer solution , its pH changes from 4.745 to 4.832. The buffer capacity is

When 2mol of HCI is added to 1L of an acidic buffer, its pH changes from 3.4 to 2.9 . The buffer capacity of the buffer solution is

100mL of a buffer solution contains 0.1M each of weak acid HA and salt NaA . How many gram of NaOH should be added to the buffer so that it pH will be 6 ? (K_(a) of HA = 10^(-5)) .

When a small amount of HCI is added to a buffer solution of acetic acid and sodium acetate

pH of a buffer solution decreases by 0.02 units when 0.12 g of acetic acid is added to 250 mL of a buffer solution of acetic and potassium acetate at 27^(@)C . The buffer capacity of the solution is

10 ml of 0.2 M acid is added to 250 ml of a buffer solution with pH = 6.34 and the pH of the solution becomes 6.32 . The buffer capacity of the solution is :

CENGAGE CHEMISTRY ENGLISH-IONIC EQUILIBRIUM-Archives Subjective
  1. Consider a buffer solution containing 0.1mol each of acetic and sodium...

    Text Solution

    |

  2. How much moles of sodium propionate should be added to 1L of an aqueou...

    Text Solution

    |

  3. Given reason for the statement that the pH of an aqueous solution of s...

    Text Solution

    |

  4. 20 mL of 0.2M sodium hydroxide is added to 50 mL of 0.2 M acetic acid ...

    Text Solution

    |

  5. K(a) for HA is 4.9 xx 10^(-8). After making the necessary approximatio...

    Text Solution

    |

  6. A solution contains a mixture of Ag^(+)(0.10M) and Hg(2)^(2+)(0.10M) w...

    Text Solution

    |

  7. The concentration of hydrogen ions in a 0.2M solution of formic acid i...

    Text Solution

    |

  8. The solubility of Mg( OH)2 in pure water is 9.57 xx 10 ^(-3) g L^(-...

    Text Solution

    |

  9. What is the pH of the solution when 0.20 mol of HCI is added to 1L of ...

    Text Solution

    |

  10. How many moles of HCl will be required to preapare one litre of a buf...

    Text Solution

    |

  11. Freshly prepared aluminium and magnesium hydroxides are stirred vigoro...

    Text Solution

    |

  12. What is the pH of 1M solution of acetic acid. To what volume one litre...

    Text Solution

    |

  13. A 50 mL solution of weak base BOH is titrated with 0.1N HCI solution. ...

    Text Solution

    |

  14. The K(SP) of Ag(2)C(2)O(4) at 25^(@)C is 1.29xx10^(-11)mol^(3)L^(-3). ...

    Text Solution

    |

  15. The solubility product K(sp) of Ca (OH)2 " at " 25^(@) C " is " ...

    Text Solution

    |

  16. The ph of blood stream is maintained by a proper balance of H(2)CO(3) ...

    Text Solution

    |

  17. An aqueous solution of a metal bromode MBr(2) (0.05M) is saturated wit...

    Text Solution

    |

  18. For the reaction Ag(CN)(2)^(ɵ)hArr Ag^(o+)+2CN^(ɵ), the K(c ) at 25^...

    Text Solution

    |

  19. Calculate the pH of an aqueous solution of 1.0M ammonium formate assum...

    Text Solution

    |

  20. What is the pH of a 0.50M aqueous NaCN solution ? (pK(b)of CN^(-)=4.70...

    Text Solution

    |

  21. The ionization constant of overset(o+)(NH(4)) ion in water is 5.6 xx 1...

    Text Solution

    |