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Using CO(2), NH(3),NH(4)NO(3), and K(2)C...

Using `CO_(2), NH_(3),NH_(4)NO_(3)`, and `K_(2)CrO_(4)` as the only reagents, devise a qualitative analysis scheme for separating and identifying the following ions, which might all be present in the same mixture: `Ba^(2+), Ca^(2+), Mg^(2+), Na^(o+), Pb^(2+)`. Assume that each cation present is `0.10M`. State the conditions of `pH` and the reagent concentration which are required in each step.

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### Step-by-Step Solution: 1. **Initial Reaction with Ammonia (NH3) and Ammonium Nitrate (NH4NO3)**: - **Objective**: To precipitate Lead (Pb²⁺). - **Conditions**: - pH should be adjusted to around 9-10 using NH3. - The concentration of NH3 should be sufficient to maintain this pH (approximately 0.1 M). - **Reaction**: Pb²⁺ reacts with OH⁻ to form Pb(OH)₂, which is a white precipitate. ...
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CENGAGE CHEMISTRY ENGLISH-IONIC EQUILIBRIUM-Archives Subjective
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