Home
Class 11
CHEMISTRY
Malonic acid is an organic dibasic acid ...

Malonic acid is an organic dibasic acid such as `H_(2)S` having first ionistion constant, `K_(1) = 1.42 xx 10^(-3)` and second ionisation constant, `K_(2) = 2.0 xx 10^(-6)`. Compute the divalent molanate ion concentration in:
a. `0.001M` malonic acid.
b. a solution that is `0.0001 M` in malonic acid and `0.1 M HC1`.

Text Solution

AI Generated Solution

To solve the problem of calculating the concentration of the divalent malonate ion (A²⁻) in two different scenarios involving malonic acid (H₂A), we will follow these steps: ### Part A: Concentration of A²⁻ in 0.001 M Malonic Acid 1. **Define the ionization reactions**: - The first ionization of malonic acid (H₂A) is: \[ H_2A \rightleftharpoons H^+ + HA^- ...
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 8.1|18 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 8.2|27 Videos
  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective Archive (Subjective)|3 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY ENGLISH|Exercise Assertion-Reasoning Type|1 Videos

Similar Questions

Explore conceptually related problems

The pH of a 0.1M solution of NH_(4)OH (having dissociation constant K_(b) = 1.0 xx 10^(-5)) is equal to

The hydrogen ion concentration of a 0.006 M benzoic acid solution is (K_(a) = 6 xx 10^(-5))

The dissociation constant of acetic acid is 1.8 xx 10^(-5) at 298 K. Calculate its degree of dissociation and H_3O^(+) ion concentration in its 0.1 M solution.

Calculate the H^+ ion concentration in 0.10 M acetic acid solution- Given that the dissociation constant of acetic acid in water is 1.8 xx 10^(-6) .

A monoprotic acid in a 0.1 M solution ionizes to 0.001% . Its ionisation constant is

Calculate the pH at which an acid indicator with K_(a), = 1.0 xx 10^(-4) changes colour when the indicator concentration is 2.0 xx 10^(-5) M

Calculate t the H^(+) ion concentration in 0.10 M acetic acid solution. Given that the dissociation constant of acetic acid in water is 1.8xx10^(-5)

Calculate the percentage ionization of 0.01 M acetic acid in 0.1 M HCI. K_a of acetic acid is 1.8 xx 10^(-5)

The hydrogen ion concentration in 0.2 M ethanoic acid (K_a = 2 xx 10^(-5) mol dm^(-3)) is

Find out the percentage dissociation of an acid having conc. of 10 M and dissociation constant 1.0xx10^(-3) .

CENGAGE CHEMISTRY ENGLISH-IONIC EQUILIBRIUM-Archives Subjective
  1. Malonic acid is an organic dibasic acid such as H(2)S having first ion...

    Text Solution

    |

  2. How much moles of sodium propionate should be added to 1L of an aqueou...

    Text Solution

    |

  3. Given reason for the statement that the pH of an aqueous solution of s...

    Text Solution

    |

  4. 20 mL of 0.2M sodium hydroxide is added to 50 mL of 0.2 M acetic acid ...

    Text Solution

    |

  5. K(a) for HA is 4.9 xx 10^(-8). After making the necessary approximatio...

    Text Solution

    |

  6. A solution contains a mixture of Ag^(+)(0.10M) and Hg(2)^(2+)(0.10M) w...

    Text Solution

    |

  7. The concentration of hydrogen ions in a 0.2M solution of formic acid i...

    Text Solution

    |

  8. The solubility of Mg( OH)2 in pure water is 9.57 xx 10 ^(-3) g L^(-...

    Text Solution

    |

  9. What is the pH of the solution when 0.20 mol of HCI is added to 1L of ...

    Text Solution

    |

  10. How many moles of HCl will be required to preapare one litre of a buf...

    Text Solution

    |

  11. Freshly prepared aluminium and magnesium hydroxides are stirred vigoro...

    Text Solution

    |

  12. What is the pH of 1M solution of acetic acid. To what volume one litre...

    Text Solution

    |

  13. A 50 mL solution of weak base BOH is titrated with 0.1N HCI solution. ...

    Text Solution

    |

  14. The K(SP) of Ag(2)C(2)O(4) at 25^(@)C is 1.29xx10^(-11)mol^(3)L^(-3). ...

    Text Solution

    |

  15. The solubility product K(sp) of Ca (OH)2 " at " 25^(@) C " is " ...

    Text Solution

    |

  16. The ph of blood stream is maintained by a proper balance of H(2)CO(3) ...

    Text Solution

    |

  17. An aqueous solution of a metal bromode MBr(2) (0.05M) is saturated wit...

    Text Solution

    |

  18. For the reaction Ag(CN)(2)^(ɵ)hArr Ag^(o+)+2CN^(ɵ), the K(c ) at 25^...

    Text Solution

    |

  19. Calculate the pH of an aqueous solution of 1.0M ammonium formate assum...

    Text Solution

    |

  20. What is the pH of a 0.50M aqueous NaCN solution ? (pK(b)of CN^(-)=4.70...

    Text Solution

    |

  21. The ionization constant of overset(o+)(NH(4)) ion in water is 5.6 xx 1...

    Text Solution

    |