Home
Class 11
CHEMISTRY
The acid from of an acid base indicator ...

The acid from of an acid base indicator is yellow in acid and red in basic from. What is the change in `pH` in order to change the indicator form `80%` yellow to `80%` red.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of determining the change in pH required to change the indicator from 80% yellow to 80% red, we can follow these steps: ### Step 1: Understand the Indicator System The indicator in question exists in two forms: - Acid form (HIn) which is yellow in acidic conditions. - Base form (In-) which is red in basic conditions. ### Step 2: Define the Initial and Final Conditions - **Initial Condition (Case 1)**: 80% yellow (acid form) and 20% red (base form). - **Final Condition (Case 2)**: 80% red (base form) and 20% yellow (acid form). ### Step 3: Set Up the Equations for Each Case Using the Henderson-Hasselbalch equation: 1. For Case 1 (80% yellow, 20% red): \[ \text{pH}_1 = \text{pKa} + \log\left(\frac{[\text{In}^-]}{[\text{HIn}]}\right) = \text{pKa} + \log\left(\frac{20}{80}\right) = \text{pKa} + \log\left(\frac{1}{4}\right) \] This simplifies to: \[ \text{pH}_1 = \text{pKa} - \log(4) \] 2. For Case 2 (20% yellow, 80% red): \[ \text{pH}_2 = \text{pKa} + \log\left(\frac{[\text{In}^-]}{[\text{HIn}]}\right) = \text{pKa} + \log\left(\frac{80}{20}\right) = \text{pKa} + \log(4) \] ### Step 4: Calculate the Change in pH To find the change in pH, we calculate: \[ \Delta \text{pH} = \text{pH}_2 - \text{pH}_1 \] Substituting the expressions we derived: \[ \Delta \text{pH} = \left(\text{pKa} + \log(4)\right) - \left(\text{pKa} - \log(4)\right) \] This simplifies to: \[ \Delta \text{pH} = \log(4) + \log(4) = 2 \log(4) \] Using the property of logarithms, \(2 \log(4) = \log(16)\). ### Step 5: Numerical Calculation Since \(\log(4) \approx 0.602\): \[ \Delta \text{pH} \approx 2 \times 0.602 = 1.204 \approx 1.2 \] Thus, the change in pH required to change the indicator from 80% yellow to 80% red is approximately **1.2**. ### Summary The change in pH required to change the indicator from 80% yellow to 80% red is **1.2**.

To solve the problem of determining the change in pH required to change the indicator from 80% yellow to 80% red, we can follow these steps: ### Step 1: Understand the Indicator System The indicator in question exists in two forms: - Acid form (HIn) which is yellow in acidic conditions. - Base form (In-) which is red in basic conditions. ### Step 2: Define the Initial and Final Conditions ...
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 8.5|6 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Subjective (Weak Acid And Weak Bases)|15 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 8.3|38 Videos
  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective Archive (Subjective)|3 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY ENGLISH|Exercise Assertion-Reasoning Type|1 Videos

Similar Questions

Explore conceptually related problems

An acid-base indicator has a K_(a) of 3.0 xx 10^(-5) . The acid form of the indicator is red and the basic form is blue. (a) By how much must the pH change in order to change the indicator from 75% red to 75% blue?

An acid base indicator has K_(a)=1.0xx10^(-5) the acid form of the indicator is red and the basic form is blue. Calculate the pH change required to change the colour of the indicator from 80% red to 80% blue.

The ionisation constant of an acid base indicator (a weak acid) is 1.0 xx 10^(-6) . The ionised form of the indicator is red and unionised form is blue. The p H change required to alter the colour of indicator from 80% red to 20% red is

A certain acid-base indicator is red in acid solution and blue in basic medium. At pH=5 75% of the indictor is present in the solution in its blue form. Calculate the pH at which indicator shows 90% red form ?

What fraction of an indicator Hi n is the basic form at a pH of 5 if the pK_(a) of the indicator is 6 ?

What are acid -base indicators and how do they indicate the end point of an acid -base titration?

Discuss the important theories of acid-base indicators.

State whether litmus is a common acid-base indicator or a universal indicator

80% of a first order reaction was completed in 70 min. What is the half life of the reaction?

What are acid-base indicators and how do they work? Explain with an example.

CENGAGE CHEMISTRY ENGLISH-IONIC EQUILIBRIUM-Ex 8.4
  1. a. At what pH does indicator change colour if the indicator is a weak ...

    Text Solution

    |

  2. The acid from of an acid base indicator is yellow in acid and red in b...

    Text Solution

    |

  3. Given that solubility product of BaSO(4) is 1 xx 10^(-10) will be prec...

    Text Solution

    |

  4. The K(sp) of AgC1 at 25^(@)C is 1.6 xx 10^(-9), find the solubility of...

    Text Solution

    |

  5. If solutbility of Ca(IO(3))(2) in water at 20^(@)C is 3.9gL^(-1). Calc...

    Text Solution

    |

  6. Find the solubility of Ca(IO(3))(2) is molL^(-1) in a solution contain...

    Text Solution

    |

  7. The solubility product (K(sp)) of BaSO(4) is 1.5xx10^(-9). Calculate t...

    Text Solution

    |

  8. A solution contains 1.4 xx 10^(-3)M AgNO(3). What concentration of KC1...

    Text Solution

    |

  9. If the solubility of CaSO(4) in H(2)O is 10^(-5)M, Calculate the solub...

    Text Solution

    |

  10. The concentration of Ag^(o+) ions in a saturated solution of Ag(2)C(2)...

    Text Solution

    |

  11. 500mL of 2 xx 10^(-3)M A1C1(3) and 500mol of 4 xx 10^(-2)M solution of...

    Text Solution

    |

  12. You are provided with 500mL of hard water, containing 0.005 mol of CaC...

    Text Solution

    |

  13. A lead salts is dissolved in HC1 which si 94% ionised. It is found to ...

    Text Solution

    |

  14. A solution constains Zn^(2+) ions and Cu^(2+) ions each of 0.02M. If t...

    Text Solution

    |

  15. The following pH range where the indicator shows change in colour are ...

    Text Solution

    |

  16. The following acid base titration graphs are given: (I) Which of ...

    Text Solution

    |

  17. What indicators will be suitable for the following acid-base titration...

    Text Solution

    |

  18. A solution gives the following colours with different indicators: a....

    Text Solution

    |

  19. In the titration of NH(4)OH versus HCl, the pH of the solution at equi...

    Text Solution

    |

  20. The pH indicators are

    Text Solution

    |