Home
Class 11
CHEMISTRY
Citric acid (H(3)A) is a polyprotic acid...

Citric acid `(H_(3)A)` is a polyprotic acid with `K_(1),K_(2)`, and `K_(3)` equals to `7.4 xx 10^(-4), 1.7 xx 10^(-5)`, and `4.0 xx 10^(-7)`, respectively. Calculate the `[H^(o+)], [H_(2)A^(Theta)], [HA^(2-)]`, and `[A^(3-)]` in `0.01M` citric acid.

Text Solution

AI Generated Solution

To solve the problem of calculating the concentrations of the various species in a 0.01 M solution of citric acid (H₃A), we will go through the dissociation steps of the acid and apply the equilibrium constants provided. ### Step 1: Write the Dissociation Reactions Citric acid is a triprotic acid, meaning it can donate three protons (H⁺). The dissociation reactions are as follows: 1. **First Dissociation:** \[ ...
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Subjective(Coordination Equilibria)|2 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Linked Comprehension|45 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Subjective (Hydrolysis Of Salt)|2 Videos
  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective Archive (Subjective)|3 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY ENGLISH|Exercise Assertion-Reasoning Type|1 Videos

Similar Questions

Explore conceptually related problems

The K_(a) for formic acid and acetic acid are 2.1 xx 10^(-4) and 1.1 xx 10^(-5) , respectively. Calculate relative strength of acids

Approximate p.H,0.1M aqueous H_(2)S solution when K_(1) and K_(2) for H_(2)S at 25^(@)C are 1xx10^(-7) and 1.3xx10^(-13) respectively:-

K_(1) & K_(2) for oxalic acid are 6.5 xx 10^(-2) and 6.1 xx 10^(-5) respectively . What will be the [OH^(-)] in a 0.01 M solution of sodium oxalate

K_(1) and K_(2) for dissociation of H_(2)A are 4xx10^(-3) and 1xx10^(-5) . Calculate concentration of A^(2-) ion in 0.1M H_(2)A solution. Also report [H^(+)] and pH.

Carbonic acid (H_(2)CO_(3)), a diprotic acid has K_(a1)=4.0xx10^(-7) and K_(a2)=7.0xx10^(-11). What is the [CO_(3)^(2-)] of a 0.025 M solution of carbonic acid?

Carbonic acid (H_(2)CO_(3)), a diprotic acid has K_(a1)=4.0xx10^(-7) and K_(a2)=7.0xx10^(-11). What is the [HCO_(3)^(-)] of a 0.025 M solution of carbonic acid?

Selenious acid (H_(2)SeO_(3)) , a diprotic acid has K_(a1)=3.0xx10^(-3) and K_(a2)=5.0xx10^(-8) . What is the [OH^(-)] of a 0.30 M solution of selenious acid?

For a polyprotic acid, H_(3)PO_(4) its three dissociation constanst K_(1),K_(2) and K_(3) are in the order

The dessociation cosntants of acetic acid and propionic acid are 1.0 xx 10^(-5) and 1.0 xx 10^(-6) respectively. The value of P^(K_(a)) (propionic acid) - P^(K_(a)) (Acetic acid) is

What are [H^(o+)], [A^(Theta) , and [B^(Theta)] in a solution that is 0.3M HA and 0.1M HB? K_(a) for HA and HB are 1.38 xx 10^(-4) and 1.05 xx 10^(-10) , respectively.