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Assertion (A): Due to common ion effect,...

Assertion (A): Due to common ion effect, the solubility of `HgI_(2)` is expected to be less in an aqueous solution of `KI` than in water. But `HgI_(2)` dissolves in an aqueous solution of `KI` to form a clear solution.
Reason (R) : `I^(Theta)` ions is highly polarisable.

A

If both (A) and (R) are correc, and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct but (R) is not the correct explanation of (A).

C

If (A) is correct, but (R) is incorrect.

D

If (A) is incorrect, but (R) is correct.

Text Solution

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The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the solubility of `HgI₂` is expected to be less in an aqueous solution of `KI` than in pure water due to the common ion effect. - The common ion effect indicates that the presence of a common ion (in this case, `I⁻` from `KI`) will suppress the solubility of a salt (here, `HgI₂`). 2. **Analyzing the Reaction**: - The dissolution of `HgI₂` in water can be represented as: \[ HgI₂ (s) \rightleftharpoons Hg^{2+} (aq) + 2I^{-} (aq) \] - When `KI` is added, it dissociates into `K⁺` and `I⁻` ions. The increased concentration of `I⁻` ions shifts the equilibrium to the left, reducing the solubility of `HgI₂`. 3. **Formation of Soluble Complex**: - Despite the common ion effect, `HgI₂` can still dissolve in `KI` to form a soluble complex: \[ HgI₂ + 2KI \rightarrow K_2HgI_4 (aq) \] - This complex formation explains why a clear solution is observed even in the presence of `KI`. 4. **Conclusion on Assertion**: - The assertion is correct: the solubility of `HgI₂` is expected to be less in `KI` due to the common ion effect, but it still dissolves to form a soluble complex. 5. **Understanding the Reason (R)**: - The reason states that `I⁻` ions are highly polarizable. This is true because `I⁻` is a larger ion, which makes it more polarizable. - However, the polarizability of `I⁻` does not directly explain the solubility behavior of `HgI₂` in `KI`. 6. **Conclusion on Reason**: - The reason is also correct, but it does not provide the correct explanation for the assertion. The solubility of `HgI₂` in `KI` is primarily due to the formation of the soluble complex rather than the polarizability of `I⁻`. 7. **Final Evaluation**: - Both the assertion and the reason are correct, but the reason is not the correct explanation for the assertion. Therefore, the correct answer is that both A and R are correct, but R is not the correct explanation of A. ### Final Answer: - The correct option is: **Both A and R are correct, but R is not the correct explanation of A.**

To solve the question, we need to analyze the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the solubility of `HgI₂` is expected to be less in an aqueous solution of `KI` than in pure water due to the common ion effect. - The common ion effect indicates that the presence of a common ion (in this case, `I⁻` from `KI`) will suppress the solubility of a salt (here, `HgI₂`). ...
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