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Assertion (A): pH value of HCN solution ...

Assertion (A): `pH` value of `HCN` solution decreases when `NaCN` is added to it.
Reason (R) : `NaCN` provides a common ion `CN^(Theta)`.

A

If both (A) and (R) are correc, and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct but (R) is not the correct explanation of (A).

C

If (A) is correct, but (R) is incorrect.

D

If (A) is incorrect, but (R) is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the pH value of an HCN solution decreases when NaCN is added to it. - HCN (hydrocyanic acid) is a weak acid that partially dissociates in solution to produce H⁺ ions and CN⁻ ions. 2. **Analyzing the Effect of Adding NaCN**: - NaCN (sodium cyanide) is a salt that completely dissociates in solution to provide Na⁺ ions and CN⁻ ions. - The addition of NaCN increases the concentration of the CN⁻ ion in the solution. 3. **Common Ion Effect**: - The presence of a common ion (in this case, CN⁻) will affect the dissociation of the weak acid (HCN). - According to Le Chatelier's principle, if the concentration of one of the products (CN⁻) increases, the equilibrium of the dissociation of HCN will shift to the left to counteract this change, resulting in a decrease in the concentration of H⁺ ions. 4. **Impact on pH**: - Since the concentration of H⁺ ions decreases when NaCN is added, the pH of the solution will actually increase (because pH is inversely related to the concentration of H⁺ ions). - Therefore, the assertion that the pH decreases is incorrect. 5. **Understanding the Reason (R)**: - The reason states that NaCN provides a common ion (CN⁻). - This statement is correct; NaCN does indeed provide the common ion CN⁻. 6. **Conclusion**: - The assertion (A) is incorrect because the pH of the solution increases, not decreases, when NaCN is added. - The reason (R) is correct because NaCN does provide a common ion. - Therefore, the correct answer is that assertion A is incorrect and reason R is correct. ### Final Answer: The correct option is **4**: Assertion A is incorrect, but Reason R is correct.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the pH value of an HCN solution decreases when NaCN is added to it. - HCN (hydrocyanic acid) is a weak acid that partially dissociates in solution to produce H⁺ ions and CN⁻ ions. ...
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