Home
Class 11
CHEMISTRY
Assertion (A): Addition of Ag^(o+) ions ...

Assertion (A): Addition of `Ag^(o+)` ions to a mixture of aqueous `NaCI` and `NaBr` solution will first precipitate `AgBr` rather than `AgCI`.
Reason (R) : `K_(sp) AgCI lt K_(sp) of AgBr`.

A

If both (A) and (R) are correc, and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct but (R) is not the correct explanation of (A).

C

If (A) is correct, but (R) is incorrect.

D

If (A) is incorrect, but (R) is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that when `Ag^+` ions are added to a mixture of `NaCl` and `NaBr` solutions, `AgBr` will precipitate first before `AgCl`. - We need to determine whether this statement is true or false. 2. **Understanding the Reason**: - The reason given is that the solubility product constant (`Ksp`) of `AgCl` is less than that of `AgBr`. - We need to verify if this reason is correct and if it supports the assertion. 3. **Comparing Ksp Values**: - The solubility product constant (`Ksp`) indicates how soluble a salt is in water. A lower `Ksp` value means the salt is less soluble and will precipitate more readily. - For the salts in question: - `Ksp(AgCl)` < `Ksp(AgBr)` means that `AgCl` is less soluble than `AgBr`. 4. **Analyzing Precipitation**: - When `Ag^+` ions are introduced to the solution, they will react with the halide ions present (`Cl^-` and `Br^-`). - The precipitation will occur based on which salt has a lower `Ksp`, meaning it will precipitate first. 5. **Determining the Correct Precipitation Order**: - Since `AgBr` has a higher `Ksp` than `AgCl`, it is more soluble and will precipitate after `AgCl`. - Therefore, the assertion that `AgBr` precipitates first is **false**. 6. **Conclusion**: - The assertion is incorrect because `AgCl` will precipitate first due to its lower `Ksp` value compared to `AgBr`. - The reason provided is also incorrect because it states the opposite of the actual relationship between the `Ksp` values. ### Final Answer: - Both the assertion and the reason are false.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that when `Ag^+` ions are added to a mixture of `NaCl` and `NaBr` solutions, `AgBr` will precipitate first before `AgCl`. - We need to determine whether this statement is true or false. ...
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer|10 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises True/ False|10 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct|121 Videos
  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective Archive (Subjective)|3 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY ENGLISH|Exercise Assertion-Reasoning Type|1 Videos

Similar Questions

Explore conceptually related problems

Assertion:Addition of silver ions to a mixture of aqueos sodium chloride and sodium bromide solution will first precipitate AgBr than AgCl. K_(sp) of AgCl gt K_(sp) of AgBr.

A solution is found to contain [CI^(Theta)] = 1.5 xx 10^(-1)M, [Br^(Theta)] = 5.0 xx 10^(-4)M, [CrO_(4)^(2-)] = 1.9xx 10^(-2)M . A solution of AgNO_(3) (100 % dissociated) is added to the above solution drop by drop. Which silver salt will precipiate first ? Given: K_(sp) (AgCI) = 1.5 xx 10^(-10), K_(sp) (AgBr) = 5.0 xx 10^(-13),K_(sp) (Ag_(2)CrO_(4)) =1.9 xx 10^(-12) .

The K of AgCl, AgBr and Agl are X, y and z respectively. On addition of AgNO_3 , in the equimolar solution of CI^- Br^- and I^- ions, Agl Ist appears as precipitate followed by AgBr, and then AgCl. The relation between x y and z is

Assertion (A): CuCI is more covalent than NaCI . Reason (R ): Na^(o+) ion more polarising than Cu^(o+) ion.

A solution is a mixture of 0.05 M NaCl and 0.05 M AgI. The concentration of iodide in the solution when AgCl just starts precipitating is equal to: (K_(sp)AgCl=1xx10^(-10)M^(2), K_(sp)AgI=4xx10^(-16)M^(2))

Assertion (A): The mobility of Na^(o+) is lower than that of K^(o+) ion. Reason (R): The ionic mobility depends upon the effective radius of the ion.

How much the concentration of Ag^(o+) ions in a saturated solution of AgCI diminish if such an amount of HCI is added to it that the concentration of CI^(Θ) ions in the solution becomes equal to 0.03M ? Also find the amount of AgCI precipitated at the given concentration. K_(sp) of AgCI = 1.8 xx 10^(-10) .

At 25^(@)C , after the addition of 110mL of 0.1NaCI solution to 100mL of 0.1N AgNO_(3) solution, the reduction potentilal of a silver electrode placed in it is 0.36V . Calculate the K_(sp) of AgCI . (Given: E^(Θ) Ag//Ag^(o+) =- 0.799V) .

Consider a sturated solution of silver chloride that is in contact with solid silver chloride. The solubility equilibrium can be represented as AgCl(s)hArrAg^(+)(aq.)+Cl^(-)(aq.)," "K_(sp)=[Ag^(+)(aq.)][Cl^(-)(aq.)] Where K_(sp) is clled the solubility product constant or simply the solubility product. In general, the solubility product of a compound is the product of the molar concentrations of the constituent ions, each raised to the power of its stoichiometric coefficient in the equilibrium equation. For concentrations of ions that do not necessarliy correpond to equilibrium conditions we use the reaction quotient (Q) which is clled the ion or ionic prodect (Q) to predict whether a precipitate will from. Note that (Q) has the same for as K_(sp) are QltK_(sp) Unsaturated solution Q=K_(sp) Saturated solution Qgt_(sp) Supersaturated solution, precipitate will from Determine the molar solubility of MgF_(2) from its solubility product K_(sp)=4xx10^(-9) :

Consider a sturated solution of silver chloride that is in contact with solid silver chloride. The solubility equilibrium can be represented as AgCl(s)hArrAg^(+)(aq.)+Cl^(-)(aq.)," "K_(sp)=[Ag^(+)(aq.)][Cl^(-)(aq.)] Where K_(sp) is clled the solubility product constant or simply the solubility product. In general, the solubility product of a compound is the product of the molar concentrations of the constituent ions, each raised to the power of its stoichiometric coefficient in the equilibrium equation. For concentrations of ions that do not necessarliy correpond to equilibrium conditions we use the reaction quotient (Q) which is clled the ion or ionic prodect (Q) to predict whether a precipitate will from. Note that (Q) has the same for as K_(sp) are QltK_(sp) Unsaturated solution Q=K_(sp) Saturated solution Qgt_(sp) Supersaturated solution, precipitate will from Will a precipitate from if 1 volume of 0.1 volume of 0.1 MPb^(2+) ion solution in mixed with 3 volume of 0.3 M Cl^(-) ion solution ? ["Givem":K_(sp)(PbCl_(2))=1.7xx10^(-5)M^(3)]

CENGAGE CHEMISTRY ENGLISH-IONIC EQUILIBRIUM-Exercises Assertion-Reasoning
  1. Assertion (A): S reacts with SO(3)^(2-) and forms S(2)O(3)^(2-) Reas...

    Text Solution

    |

  2. Assertion (A): The amino acid glycine predominatly exists in the form ...

    Text Solution

    |

  3. Assertion (A): Sb^(3+) is not precipitated as sulphide when H(2)S (g) ...

    Text Solution

    |

  4. Assertion (A): Addition of Ag^(o+) ions to a mixture of aqueous NaCI a...

    Text Solution

    |

  5. Assertion : The pH of an aqueous solution of acetic acid remains uncha...

    Text Solution

    |

  6. Assertion (A): On mixing equal volumes of 1M HCi and 2 M CH(3)COONa, a...

    Text Solution

    |

  7. Assertion (A): On addition of NH(4)CI to NH(4)OH, pH decreases but rem...

    Text Solution

    |

  8. Assertion (A): A is very dilute acidic solution of Cd^(2+) and Ni^(2+)...

    Text Solution

    |

  9. STATEMENT-1: In the titratio of Na(2)CO(3) with HCl using methyl orang...

    Text Solution

    |

  10. Statement: In acidic medium, Zn^(2+) is not precipitated by H(2)S. E...

    Text Solution

    |

  11. Statement: In an acid-basic titration involving a strong base and a we...

    Text Solution

    |

  12. Assertion (A): An aqueous solution of ammonium acetate acts as a buffe...

    Text Solution

    |

  13. Assertion (A): When small amount of acid or base is added to pure wate...

    Text Solution

    |

  14. Assertion (A): pH of acidic solution is always below 7 at 25^(@)C. R...

    Text Solution

    |

  15. Assertion (A): H(2)SO(4) acts as a base in the presence of HCIO(4). ...

    Text Solution

    |

  16. Assertion (A): pH of neutral solution is always 7. Reason (R) : pH o...

    Text Solution

    |

  17. Assertion (A): pH of 10^(8)M HCl is not equal to 8. Reason (R) : HCl...

    Text Solution

    |

  18. Assertion (A): If a solution with pH = 2 is diluted to double the volu...

    Text Solution

    |

  19. Assertions : When HCl gas is passed through a saturated solution of co...

    Text Solution

    |

  20. Assertion (A): pH of buffer chnages with temperature. Reason (R) : I...

    Text Solution

    |