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Assertion (A): A is very dilute acidic s...

Assertion (A): A is very dilute acidic solution of `Cd^(2+)` and `Ni^(2+)` gives yellow precipitate of `CdS` on passing hydrogen sulphide.
Reason (R) : Solubility product of `CdS` is more than that of `NiS`.

A

If both (A) and (R) are correc, and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct but (R) is not the correct explanation of (A).

C

If (A) is correct, but (R) is incorrect.

D

If (A) is incorrect, but (R) is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that a very dilute acidic solution of \( \text{Cd}^{2+} \) and \( \text{Ni}^{2+} \) gives a yellow precipitate of \( \text{CdS} \) on passing hydrogen sulfide (\( \text{H}_2\text{S} \)). **Explanation**: - When \( \text{H}_2\text{S} \) is passed through the solution, sulfide ions (\( \text{S}^{2-} \)) are produced. - \( \text{CdS} \) is known to form a yellow precipitate, while \( \text{NiS} \) forms a black precipitate. - In a very dilute solution, the concentration of \( \text{Cd}^{2+} \) and \( \text{Ni}^{2+} \) ions are similar, but \( \text{CdS} \) precipitates first due to its lower solubility product (\( K_{sp} \)). **Conclusion**: The assertion is correct. ### Step 2: Analyze the Reason The reason states that the solubility product of \( \text{CdS} \) is more than that of \( \text{NiS} \). **Explanation**: - The solubility product (\( K_{sp} \)) is a measure of how much of a compound can dissolve in solution. A lower \( K_{sp} \) value indicates that the compound is less soluble and will precipitate out of solution at a lower concentration of ions. - The experimental values show that \( K_{sp} \) of \( \text{CdS} \) is \( 8 \times 10^{-28} \) and \( K_{sp} \) of \( \text{NiS} \) is \( 3 \times 10^{-19} \). - Since \( K_{sp} \) of \( \text{CdS} \) is less than that of \( \text{NiS} \), it means \( \text{CdS} \) is less soluble and will precipitate first. **Conclusion**: The reason is incorrect. ### Final Conclusion - The assertion is correct: a yellow precipitate of \( \text{CdS} \) forms. - The reason is incorrect: \( K_{sp} \) of \( \text{CdS} \) is less than that of \( \text{NiS} \). Thus, the correct answer is that the assertion is correct but the reason is incorrect. ### Answer: Assertion (A) is correct, Reason (R) is incorrect.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that a very dilute acidic solution of \( \text{Cd}^{2+} \) and \( \text{Ni}^{2+} \) gives a yellow precipitate of \( \text{CdS} \) on passing hydrogen sulfide (\( \text{H}_2\text{S} \)). **Explanation**: - When \( \text{H}_2\text{S} \) is passed through the solution, sulfide ions (\( \text{S}^{2-} \)) are produced. - \( \text{CdS} \) is known to form a yellow precipitate, while \( \text{NiS} \) forms a black precipitate. ...
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